1-氯甲基-1,4-二氮杂二环[2.2.2]辛烷氯化物
化合物
1-氯甲基-1,4-二氮杂二环[2.2.2]辛烷氯化物是一种季铵盐，化学式为C7H14Cl2N2。它可由1,4-二氮杂二环[2.2.2]辛烷和二氯甲烷回流反应得到，[1]它和溴在乙腈中反应，可以得到1:1的加合物。[2]它和氯化锌或氯化钴在盐酸中反应，可以得到1-氯甲基-1,4-二铵杂二环[2.2.2]辛烷四氯合锌（钴）酸盐。[3]
| 1-氯甲基-1,4-二氮杂二环[2.2.2]辛烷氯化物 | |
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-1,4-diazabicyclo(2.2.2)octan-1-ium_chloride.svg)
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| 别名 | 1-氯甲基-1-铵杂-4-氮杂二环[2.2.2]辛烷氯化物(1:1) 1-氯甲基-1,4-二氮杂二环[2.2.2]辛烷-1-鎓氯化物 |
| 识别 | |
| CAS号 | 36273-11-7 
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| 性质 | |
| 化学式 | C7H14Cl2N2 |
| 摩尔质量 | 197.11 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献 编辑
- ^ Laali, Kenneth K.; Jamalian, Arezu; Zhao, Chunqing. Reaction of Selectfluor (F-TEDA-BF4) with chloromethylated-DABCO monocation salts (X=BF4, NTf2) and other nitrogen bases (Et3N; piperidine; basic ionic liquid); unexpected formation of symmetrical [N−H−N]+ trication salts. Tetrahedron Letters (Elsevier BV). 2014, 55 (49): 6643–6646. ISSN 0040-4039. doi:10.1016/j.tetlet.2014.10.071.
- ^ Luis‐Barrera, Javier; Rodriguez, Sandra; Uria, Uxue; Reyes, Efraim; Prieto, Liher; Carrillo, Luisa; Pedrón, Manuel; Tejero, Tomás; Merino, Pedro; Vicario, Jose L. Brønsted Acid versus Phase‐Transfer Catalysis in the Enantioselective Transannular Aminohalogenation of Enesultams. Chemistry – A European Journal (Wiley). 2022-10-17, 28 (62). ISSN 0947-6539. doi:10.1002/chem.202202267.
- ^ Chen, Chun-Hong; Xu, Guan-Cheng. Synthesis, characterization and disorder–order phase transition of inorganic–organic hybrid materials (H2dabco-CH2-Cl)[MIICl4] (M = Co, Zn). CrystEngComm (Royal Society of Chemistry (RSC)). 2016, 18 (4): 550–557. ISSN 1466-8033. doi:10.1039/c5ce02059j.