4-甲基叔丁苯
4-甲基叔丁苯是一种有机化合物，化学式为C11H16。它可由氢气在钯催化下还原4-叔丁基苯甲醛得到[2][3]，或在酸催化下由2-甲基丙烯和甲苯反应制得。[4]在相转移催化剂和氯化钴催化下，它可以被氧气氧化为4-叔丁基苯甲酸。[5]它在混酸中硝化，可以得到3-硝基-4-甲基叔丁苯。[6]
| 4-甲基叔丁苯 | |
|---|---|
| |
| 别名 | 4-叔丁基甲苯 对甲基叔丁苯 |
| 识别 | |
| CAS号 | 98-51-1 
|
| 性质 | |
| 化学式 | C11H16 |
| 摩尔质量 | 148.24 g·mol−1 |
| 密度 | 0.8612 g/cm3（20 °C）[1] |
| 熔点 | −52 °C（221 K）[1] |
| 沸点 | 193 °C（466 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献 编辑
- ^ 1.0 1.1 1.2 "Hazardous Substances Data Bank" data were obtained from the National Library of Medicine (US). Retrieved from SciFinder. [2021-12-24].
- ^ Shuguo Wang, Peng Zhou, Liang Jiang, Zehui Zhang, Kejian Deng, Yuhua Zhang, Yanxi Zhao, Jinlin Li, Steven Bottle, Huaiyong Zhu. Selective deoxygenation of carbonyl groups at room temperature and atmospheric hydrogen pressure over nitrogen-doped carbon supported Pd catalyst. Journal of Catalysis. 2018-12, 368: 207–216 [2021-12-24]. doi:10.1016/j.jcat.2018.10.017 （英语）.
- ^ Giorgio La Sorella, Laura Sperni, Patrizia Canton, Lisa Coletti, Fabrizio Fabris, Giorgio Strukul, Alessandro Scarso. Selective Hydrogenations and Dechlorinations in Water Mediated by Anionic Surfactant-Stabilized Pd Nanoparticles. The Journal of Organic Chemistry. 2018-07-20, 83 (14): 7438–7446 [2021-12-24]. ISSN 0022-3263. doi:10.1021/acs.joc.8b00314. （原始内容存档于2019-05-02） （英语）.
- ^ Fu, Xiangkai; Pu, Wanli; Luo, Bikuei; Deng, Chuanyue. Perfluorooctanesulfonic acid catalyzed Friedel-Crafts alkylation with olefins in gas-liquid phase. Chinese Chemical Letters, 1993. 4 (4): 307-310.
- ^ Nimer Taha, Mandan Chidambaram, Jihad Dakka, Yoel Sasson. Co(II) Catalyzed Solvent Free Auto-Oxidation of Methylbenzenes to Substituted Benzoic Acids Under Phase Transfer Conditions. Catalysis Letters. 2009-05, 129 (3-4): 358–362 [2021-12-24]. ISSN 1011-372X. doi:10.1007/s10562-009-9874-5 （英语）.
- ^ J. V. N. Vara Prasad. Synthesis of Heterocyclic Thiosulfonates. Organic Letters. 2000-04-01, 2 (8): 1069–1072 [2021-12-24]. ISSN 1523-7060. doi:10.1021/ol0056170. （原始内容存档于2021-12-24） （英语）.