4-碘苯胺
化合物
4-碘苯胺是一种有机化合物，化学式为C6H6IN，它是三种碘苯胺的同分异构体之一。它可由4-硝基碘苯被氢气、硼氢化钠等还原剂还原得到。[2][3]它和苯甲醛在乙醇中反应，可以得到N-亚苄基-4-碘苯胺。[4]在钯催化下、碳酸钾存在下，它和苯硼酸发生偶联反应，可以得到4-氨基联苯。[5]
| 4-碘苯胺 | |
|---|---|
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| 识别 | |
| CAS号 | 540-37-4 
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| SMILES |
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| 性质 | |
| 化学式 | C6H6IN |
| 摩尔质量 | 219.02 g·mol−1 |
| 熔点 | 66 °C（339 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献 编辑
- ^ Shoji Kajigaeshi, Takaaki Kakinami, Hiromichi Yamasaki, Shizuo Fujisaki, Tsuyoshi Okamoto. Halogenation Using Quaternary Ammonium Polyhalides. VII. Iodination of Aromatic Amines by Use of Benzyltrimethylammonium Dichloroiodate(1—). Bulletin of the Chemical Society of Japan. 1988-02, 61 (2): 600–602 [2021-11-15]. ISSN 0009-2673. doi:10.1246/bcsj.61.600. （原始内容存档于2021-11-15） （英语）.
- ^ Wenjun Yu, Lan-Lan Lou, Shanshan Li, Tianyuan Ma, Lezi Ouyang, Li Feng, Shuangxi Liu. Highly efficient and durable platinum nanocatalysts stabilized by thiol-terminated poly(N-isopropyl acrylomide) for selective hydrogenation of halonitrobenzene to haloaniline. RSC Advances. 2017, 7 (2): 751–757 [2021-11-15]. ISSN 2046-2069. doi:10.1039/C6RA24773C （英语）.
- ^ Sanya Pachisia, Ram Kishan, Samanta Yadav, Rajeev Gupta. Half-Sandwich Ruthenium Complexes of Amide-Phosphine Based Ligands: H-Bonding Cavity Assisted Binding and Reduction of Nitro-substrates. Inorganic Chemistry. 2021-02-01, 60 (3): 2009–2022 [2021-11-15]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.0c03505. （原始内容存档于2021-11-01） （英语）.
- ^ Romero, Eugenie; Oueslati, Saoussen; Benchekroun, Mohamed; D'Hollander, Agathe C. A.; Ventre, Sandrine; Vijayakumar, Kamsana; Minard, Corinne; Exilie, Cynthia; Tlili, Linda; Retailleau, Pascal; Zavala, Agustin; Elisee, Eddy; Selwa, Edithe; Nguyen, Laetitia A.; Pruvost, Alain; Naas, Thierry; Iorga, Bogdan I.; Dodd, Robert H.; Cariou, Kevin. Azetidinimines as a novel series of non-covalent broad-spectrum inhibitors of β-lactamases with submicromolar activities against carbapenemases of classes A, B and D. ChemRxiv, 2020. 1-31.
- ^ Hongxue Xie, Huihui Liu, Meimei Wang, Hui Pan, Caixia Gao. L‐Tyrosine‐Pd complex supported on Fe 3 O 4 magnetic nanoparticles: A new catalyst for C–C coupling and Synthesis of sulfides. Applied Organometallic Chemistry. 2020-01, 34 (1) [2021-11-15]. ISSN 0268-2605. doi:10.1002/aoc.5256. （原始内容存档于2021-11-15） （英语）.