三苯基氯硅烷

三苯基氯硅烷是一种有机硅化合物，化学式为(C₆H₅)₃SiCl。

制备编辑

三苯基氯硅烷最初于1886年由A. Polis用五氯化磷和四苯基硅烷按化学计量比反应得到：^[3]

\mathrm {Si(C_{6}H_{5})_{4}\ +PCl_{5}\longrightarrow Si(C_{6}H_{5})_{3}Cl+\ Cl{-}C_{6}H_{5}\ +\ PCl_{3}}

它也可由苯基氯化镁和四氯化硅反应得到：

\mathrm {3\ ClMgC_{6}H_{5}+SiCl_{4}\longrightarrow Si(C_{6}H_{5})_{3}Cl+\ 3\ MgCl_{2}}

三苯基氯硅烷可以和5-溴-1,3-苯二酚在二氯甲烷中反应，得到5-溴-1,3-二(三苯基硅氧基)苯。^[4]

^ Speier, John L.; Zimmerman, Ruth E. Disproportionation of Phenylsilanes with Aluminum Chloride as the Catalyst. Journal of the American Chemical Society. 1955, 77 (23): 6395–6396. ISSN 0002-7863. doi:10.1021/ja01628a110.
^ Bochkarev, V. N.; Turetskaya, R. A.; Troitskaya, N. N.; Luskina, B. M.; Savushkina, V. I.; Korablina, T. P.; Dzvonar, V. G.; Chernysheva, N. I. High-boiling by-products from the synthesis of phenylchlorosilanes. Zhurnal Obshchei Khimii, 1983. 53 (4): 824-827. ISSN: 0044-460X
^ A. Polis: Ueber aromatische Siliciumverbindungen（德文）. In: Berichte der deutschen chemischen Gesellschaft. Band 19, Nr. 1, Januar 1886, S. 1012–1024,
^ Pekarek, Ryan T.; Celio, Hugo; Rose, Michael J. Synthetic Insights into Surface Functionalization of Si(111)–R Photoelectrodes: Steric Control and Deprotection of Molecular Passivating Layers. Langmuir. 2018, 34 (22): 6328–6337. ISSN 0743-7463. doi:10.1021/acs.langmuir.7b03564.