二(二苯乙烯二硫醇)镍

二(二苯乙烯二硫醇)镍
别名	二[1,2-二苯基-1,2-乙烯二硫醇]镍
识别
CAS号	28984-20-5
PubChem	5374634
ChemSpider	44211332
SMILES	C1=CC=C(C=C1)/C(=C(/[S-])\C2=CC=CC=C2)/[S-].C1=CC=C(C=C1)/C(=C(/[S-])\C2=CC=CC=C2)/[S-].[Ni];
性质
化学式	C28H20NiS4
摩尔质量	543.41 g·mol−1
外观	黑绿色固体
密度	1.466 g/cm3
熔点	260 °C（533 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

二(二苯乙烯二硫醇)镍是一种配位化合物，化学式为Ni(S₂C₂Ph₂)₂（其中Ph为苯基）。它是黑色固体，在甲苯中形成绿色溶液。它是二(烯烃二硫醇)类配体（Ni(S₂C₂R₂)₂，R为烃基或芳基）的一员，这类配体属于noninnocent配体。^[1]该分子骨架中C-S和C-C键的键长分别为1.71和1.39 Å，长度介于单双键之间。^[2]

该配合物可由二苯基乙炔和硫化镍反应制得。^[3]其它制法包括镍盐和硫化苯偶姻的反应。该配合物和其它配体反应，得到单(烯烃二硫醇)配合物Ni(S₂C₂Ph₂)L₂。^[4]

参考文献编辑

^ Karlin, K. D.; Stiefel, E. I., Eds. “Progress in Inorganic Chemistry, Dithiolene Chemistry: Synthesis, Properties, and Applications” Wiley-Interscience: New York, 2003. ISBN 0-471-37829-1
^ Miao, Qingqing; Gao, Junxiong; Wang, Zeqing; Yu, Hang; Luo, Yi; Ma, Tingli. Syntheses and Characterization of Several Nickel Bis(dithiolene) Complexes with Strong and Broad Near-IR Absorption. Inorganica Chimica Acta. 2011, 376: 619–627. doi:10.1016/j.ica.2011.07.046.
^ Schrauzer, G. N.; Mayweg, V. Reaction of Diphenylacetylene with Nickel Sulfides. Journal of the American Chemical Society. 1962, 84 (16): 3221. doi:10.1021/ja00875a061.
^ Obanda, Antony; Martinez, Kristina; Schmehl, Russell H.; Mague, Joel T.; Rubtsov, Igor V.; MacMillan, Samantha N.; Lancaster, Kyle M.; Sproules, Stephen; Donahue, James P. Expanding the Scope of Ligand Substitution from [M(S2C2Ph2] (M = Ni²⁺, Pd²⁺, Pt²⁺) to Afford New Heteroleptic Dithiolene Complexes (PDF). Inorganic Chemistry. 2017, 56 (17): 10257–10267 [2019-12-27]. PMID 28820242. doi:10.1021/acs.inorgchem.7b00971. （原始内容存档 (PDF)于2019-04-26）.

[1] Karlin, K. D.; Stiefel, E. I., Eds. “Progress in Inorganic Chemistry, Dithiolene Chemistry: Synthesis, Properties, and Applications” Wiley-Interscience: New York, 2003. ISBN 0-471-37829-1

[2] Miao, Qingqing; Gao, Junxiong; Wang, Zeqing; Yu, Hang; Luo, Yi; Ma, Tingli. Syntheses and Characterization of Several Nickel Bis(dithiolene) Complexes with Strong and Broad Near-IR Absorption. Inorganica Chimica Acta. 2011, 376: 619–627. doi:10.1016/j.ica.2011.07.046.

[3] Schrauzer, G. N.; Mayweg, V. Reaction of Diphenylacetylene with Nickel Sulfides. Journal of the American Chemical Society. 1962, 84 (16): 3221. doi:10.1021/ja00875a061.

[4] Obanda, Antony; Martinez, Kristina; Schmehl, Russell H.; Mague, Joel T.; Rubtsov, Igor V.; MacMillan, Samantha N.; Lancaster, Kyle M.; Sproules, Stephen; Donahue, James P. Expanding the Scope of Ligand Substitution from [M(S2C2Ph2] (M = Ni²⁺, Pd²⁺, Pt²⁺) to Afford New Heteroleptic Dithiolene Complexes (PDF). Inorganic Chemistry. 2017, 56 (17): 10257–10267 [2019-12-27]. PMID 28820242. doi:10.1021/acs.inorgchem.7b00971. （原始内容存档 (PDF)于2019-04-26）.

[1]

[2]

[3]

[4]

二(二苯乙烯二硫醇)镍

参考文献 编辑

参考文献编辑