六氰合钴(III)酸镍(II)

六氰合钴(III)酸镍(II)
识别
CAS号	14074-48-7
性质
化学式	Ni3[Co(CN)6]2
摩尔质量	606.161 g·mol⁻¹
外观	浅蓝色固体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

六氰合钴(III)酸镍(II)是一种无机化合物，化学式为Ni₃[Co(CN)₆]₂。它可由六氰合钴(III)酸钾和氯化镍^[1]、硫酸镍^[2]或硝酸镍^[3]反应，经过滤、洗涤后得到。一些文献在制备时会加入柠檬酸钠。^[1]^[4]该配合物它在高温下可以分解。^[5]它可用于制备(Ni,Co)Se₂纳米材料。^[4]

参考文献编辑

^ ^1.0 ^1.1 ^1.2 Gang Huang, Dongming Yin, Feifei Zhang, Qian Li, Limin Wang. Yolk@Shell or Concave Cubic NiO–Co 3 O 4 @C Nanocomposites Derived from Metal–Organic Frameworks for Advanced Lithium-Ion Battery Anodes. Inorganic Chemistry. 2017-08-21, 56 (16): 9794–9801 [2019-06-25]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.7b01296 （英语）.
^ E. Reguera, E. Marín, A. Calderón, J. Rodríguez-Hernández. Photo-induced charge transfer in Prussian blue analogues as detected by photoacoustic spectroscopy. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2007-09, 68 (1): 191–197 [2019-06-25]. doi:10.1016/j.saa.2006.11.013. （原始内容存档于2018-06-28）（英语）.
^ Satish K. Nune, Praveen K. Thallapally, Benard Peter McGrail, Harsha V. R. Annapureddy, Liem X. Dang, Donghai Mei, Naveen Karri, Kyle J. Alvine, Matthew J. Olszta, Bruce W. Arey, Alice Dohnalkova. Adsorption Kinetics in Nanoscale Porous Coordination Polymers. ACS Applied Materials & Interfaces. 2015-10-07, 7 (39): 21712–21716 [2019-06-25]. ISSN 1944-8244. doi:10.1021/acsami.5b04109 （英语）.
^ ^4.0 ^4.1 Xun Xu, Hanfeng Liang, Fangwang Ming, Zhengbing Qi, Yaqiang Xie, Zhoucheng Wang. Prussian Blue Analogues Derived Penroseite (Ni,Co)Se 2 Nanocages Anchored on 3D Graphene Aerogel for Efficient Water Splitting. ACS Catalysis. 2017-09, 7 (9): 6394–6399 [2019-06-25]. ISSN 2155-5435. doi:10.1021/acscatal.7b02079 （英语）.
^ Tribunescu, P.; Pirlea, Gh. Kinetics of the thermal decomposition of cobalt and nickel hexacyanocobaltates and mixed cobalt-thallium and nickel-thallium hexacyanocobaltates（罗马尼亚文）. Buletinul Stiintific si Tehnic al Institutului Politehnic Traian Vuia Timisoara, 1969. 14 (2): 561-567. ISSN: 0563-5594.

[Huang-1] 1.0 ^1.1 ^1.2 Gang Huang, Dongming Yin, Feifei Zhang, Qian Li, Limin Wang. Yolk@Shell or Concave Cubic NiO–Co 3 O 4 @C Nanocomposites Derived from Metal–Organic Frameworks for Advanced Lithium-Ion Battery Anodes. Inorganic Chemistry. 2017-08-21, 56 (16): 9794–9801 [2019-06-25]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.7b01296 （英语）.

[2] E. Reguera, E. Marín, A. Calderón, J. Rodríguez-Hernández. Photo-induced charge transfer in Prussian blue analogues as detected by photoacoustic spectroscopy. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2007-09, 68 (1): 191–197 [2019-06-25]. doi:10.1016/j.saa.2006.11.013. （原始内容存档于2018-06-28）（英语）.

[3] Satish K. Nune, Praveen K. Thallapally, Benard Peter McGrail, Harsha V. R. Annapureddy, Liem X. Dang, Donghai Mei, Naveen Karri, Kyle J. Alvine, Matthew J. Olszta, Bruce W. Arey, Alice Dohnalkova. Adsorption Kinetics in Nanoscale Porous Coordination Polymers. ACS Applied Materials & Interfaces. 2015-10-07, 7 (39): 21712–21716 [2019-06-25]. ISSN 1944-8244. doi:10.1021/acsami.5b04109 （英语）.

[Xu-4] 4.0 ^4.1 Xun Xu, Hanfeng Liang, Fangwang Ming, Zhengbing Qi, Yaqiang Xie, Zhoucheng Wang. Prussian Blue Analogues Derived Penroseite (Ni,Co)Se 2 Nanocages Anchored on 3D Graphene Aerogel for Efficient Water Splitting. ACS Catalysis. 2017-09, 7 (9): 6394–6399 [2019-06-25]. ISSN 2155-5435. doi:10.1021/acscatal.7b02079 （英语）.

[5] Tribunescu, P.; Pirlea, Gh. Kinetics of the thermal decomposition of cobalt and nickel hexacyanocobaltates and mixed cobalt-thallium and nickel-thallium hexacyanocobaltates（罗马尼亚文）. Buletinul Stiintific si Tehnic al Institutului Politehnic Traian Vuia Timisoara, 1969. 14 (2): 561-567. ISSN: 0563-5594.

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六氰合钴(III)酸镍(II)

参考文献 编辑

参考文献编辑