4-硝基苯甲醛

4-硝基苯甲醛
	IUPAC名; 4-Nitrobenzaldehyde
别名	p-Nitrobenzaldehyde
性质
化学式	C7H5NO3
摩尔质量	151.12 g·mol−1
外观	略带黄色的晶体粉末
密度	1.546 g/cm3
熔点	103—106 °C（376—379 K）
沸点	300 °C（573 K）
磁化率	−66.57·10−6 cm3/mol
识别
CAS号	555-16-8
PubChem	541
ChemSpider	526
SMILES	O=[N+]([O-])c1ccc(C=O)cc1;
InChI	1/C7H5NO3/c9-5-6-1-3-7(4-2-6)8(10)11/h1-5H;
InChIKey	BXRFQSNOROATLV-UHFFFAOYAO
ChEBI	66926
危险性
	GHS危险性符号;
H-术语	H317, H319
P-术语	P280, P305+351+338
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

4-硝基苯甲醛是一种有机化合物，化学式为C₇H₅NO₃，可以以4-硝基甲苯为原料制得。^[3]

它可以被水合肼在乙醇中还原为4-氨基苯甲醛，^[4]或被硼氢化钠还原为4-硝基苯甲醇，^[5]硼氢化钠也可将其还原为4-氨基苯甲醇^[6]。它可以被过氧化氢氧化为4-硝基苯甲酸。^[7]

参考文献编辑

^ ^1.0 ^1.1 4-Nitrobenzaldehyde(555-16-8) (Date Accessed 17 April 2013)
^ ^2.0 ^2.1 来源：Sigma-Aldrich Co., 4-Nitrobenzaldehyde （4 May 2011查阅）.
^ 4-Nitrobenzaldehyd （页面存档备份，存于互联网档案馆）, Versuchsvorschrift aus: Organic Syntheses, Coll. Vol. 2, p. 441 (1943); Vol. 18, p. 61 (1938).
^ Shuo Chen, Li-Li Ling, Shun-Feng Jiang, Hong Jiang. Selective hydrogenation of nitroarenes under mild conditions by the optimization of active sites in a well defined Co@NC catalyst. Green Chemistry. 2020, 22 (17): 5730–5741 [2021-05-18]. ISSN 1463-9262. doi:10.1039/D0GC01835J （英语）.
^ Naimi-Jamal, M. R.; Mokhtari, J.; Dekamin, Mohammad G. Fast and efficient method for quantitative reduction of carbonyl compounds by NaBH4 under solvent-free conditions. Proceedings of the International Electronic Conference on Synthetic Organic Chemistry, 11th, Nov. 1-30, 2007: a017/1-a017/5. ISBN 3-906980-19-7.
^ Wei-Guo Jia, Mei Li, Xue-Ting Zhi, Li-Li Gao, Jun Du. Copper(II) complex with oxazoline ligand: Synthesis, structures and catalytic activity for nitro compounds reduction. Journal of Molecular Structure. 2020-10, 1217: 128349 [2021-05-18]. doi:10.1016/j.molstruc.2020.128349. （原始内容存档于2020-05-09）（英语）.
^ Sagar Sharma, Nilotpal Barooah, Jubaraj B. Baruah. Tris(3,5-dimethylpyrazole)copper(II) nitrate: as an oxidation catalyst. Journal of Molecular Catalysis A: Chemical. 2005-03, 229 (1-2): 171–176 [2021-05-18]. doi:10.1016/j.molcata.2004.11.019. （原始内容存档于2018-06-05）（英语）.

[ChemicalBook-1] 1.0 ^1.1 4-Nitrobenzaldehyde(555-16-8) (Date Accessed 17 April 2013)

[SigmaAldrich-2] 2.0 ^2.1 来源：Sigma-Aldrich Co., 4-Nitrobenzaldehyde （4 May 2011查阅）.

[3] 4-Nitrobenzaldehyd （页面存档备份，存于互联网档案馆）, Versuchsvorschrift aus: Organic Syntheses, Coll. Vol. 2, p. 441 (1943); Vol. 18, p. 61 (1938).

[4] Shuo Chen, Li-Li Ling, Shun-Feng Jiang, Hong Jiang. Selective hydrogenation of nitroarenes under mild conditions by the optimization of active sites in a well defined Co@NC catalyst. Green Chemistry. 2020, 22 (17): 5730–5741 [2021-05-18]. ISSN 1463-9262. doi:10.1039/D0GC01835J （英语）.

[5] Naimi-Jamal, M. R.; Mokhtari, J.; Dekamin, Mohammad G. Fast and efficient method for quantitative reduction of carbonyl compounds by NaBH4 under solvent-free conditions. Proceedings of the International Electronic Conference on Synthetic Organic Chemistry, 11th, Nov. 1-30, 2007: a017/1-a017/5. ISBN 3-906980-19-7.

[6] Wei-Guo Jia, Mei Li, Xue-Ting Zhi, Li-Li Gao, Jun Du. Copper(II) complex with oxazoline ligand: Synthesis, structures and catalytic activity for nitro compounds reduction. Journal of Molecular Structure. 2020-10, 1217: 128349 [2021-05-18]. doi:10.1016/j.molstruc.2020.128349. （原始内容存档于2020-05-09）（英语）.

[7] Sagar Sharma, Nilotpal Barooah, Jubaraj B. Baruah. Tris(3,5-dimethylpyrazole)copper(II) nitrate: as an oxidation catalyst. Journal of Molecular Catalysis A: Chemical. 2005-03, 229 (1-2): 171–176 [2021-05-18]. doi:10.1016/j.molcata.2004.11.019. （原始内容存档于2018-06-05）（英语）.

[3]

[1]

[2]

[4]

[5]

[6]

[7]

4-硝基苯甲醛

参考文献 编辑

参考文献编辑