氰化铝
氰化铝是一种无机化合物，化学式为Al(CN)3。它可由氰化氢和氢化铝反应制得。[1]四氯合铝酸锂和三甲基氰硅烷在乙醚中反应，也能得到氰化铝。[2]金属铝和氰化汞在液氨中反应，可以得到氰化铝的氨合物。[3]它在水中水解，生成氢氧化铝和氰化氢；[1]它难溶于吡啶。[4]
| 氰化铝 | |
|---|---|
| |
| IUPAC名 Aluminium tricyanide | |
| 识别 | |
| CAS号 | 87993-97-3 
|
| PubChem | 21122287 |
| ChemSpider | 19984794 |
| SMILES |
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| 性质 | |
| 化学式 | C3AlN3 |
| 摩尔质量 | 105.03 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献 编辑
- ^ 1.0 1.1 Wittig, Georg; Bille, Heinz. Aluminum tricyanide and lithium aluminum tetracyanide. Zeitschrift fuer Naturforschung, 1951. 6B. 226. ISSN: 0372-9516.
- ^ Darrick Williams, Brett Pleune, Kurt Leinenweber, J. Kouvetakis. Synthesis and Structural Properties of the Binary Framework C–N Compounds of Be, Mg, Al, and Tl. Journal of Solid State Chemistry. 2001-06, 159 (1): 244–250 [2020-06-26]. doi:10.1006/jssc.2001.9192. （原始内容存档于2018-06-04） （英语）.
- ^ Bergstrom, F. W. The Reaction Between Mercuric Cyanide and Certain Metals in Liquid Ammonia. Journal of the American Chemical Society. July 1924, 46 (7): 1559–1568. doi:10.1021/ja01672a002.
- ^ A. V. G. Chizmeshya, C. J. Ritter, T. L. Groy, J. B. Tice, J. Kouvetakis. Synthesis of Molecular Adducts of Beryllium, Boron, and Gallium Cyanides: Theoretical and Experimental Correlations between Solid-State and Molecular Analogues. Chemistry of Materials. 2007-11, 19 (24): 5890–5901 [2020-06-26]. ISSN 0897-4756. doi:10.1021/cm071275h （英语）.