苯乙酮肟

苯乙酮肟
识别
CAS号	613-91-2
性质
熔点	59—60 °C（332—333 K）
沸点	200—202 °C（473—475 K）; 120—125 °C（393—398 K）（分解）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

苯乙酮肟是一种有机化合物，化学式为C₈H₉NO。它可由苯乙酮和盐酸羟胺在乙酸钠存在下反应得到。^[4]在四氯化钛催化下，它可以发生重排反应，得到乙酰苯胺。^[5]它和二氧化氮反应，可以得到苯乙酮。^[6]

参考文献编辑

^ Nidhi Jain, Anil Kumar, Shive M.S. Chauhan. Metalloporphyrin and heteropoly acid catalyzed oxidation of CNOH bonds in an ionic liquid: biomimetic models of nitric oxide synthase. Tetrahedron Letters. 2005-04, 46 (15): 2599–2602 [2022-01-16]. doi:10.1016/j.tetlet.2005.02.088 （英语）.
^ Hajipour, A. R.; Zahmatkesh, S.; Ruoho, A. E. Methyltriphenylphosphonium peroxydisulfate (MTPPP): A mild and inexpensive reagent for the cleavage of oximes, phenylhydrazones and 2,4-dinitrophenylhydrazones to the corresponding carbonyl compounds under non-aqueous conditions. Journal of the Iranian Chemical Society, 2008. 5. pp S54~S58. ISSN 1735-207X.
^ Henry Stephen, Benjamin Staskun. 204. A new mechanism for the Beckmann rearrangement of ketoximes. Journal of the Chemical Society (Resumed). 1956: 980 [2022-01-16]. ISSN 0368-1769. doi:10.1039/jr9560000980 （英语）.
^ Marcin Szewczyk, Agata Bezłada, Jacek Mlynarski. Zinc-Catalyzed Enantioselective Hydrosilylation of Ketones and Imines under Solvent-Free Conditions. ChemCatChem. 2016-12-07, 8 (23): 3575–3579 [2022-01-16]. doi:10.1002/cctc.201601140 （英语）.
^ S. Katkevica, A. Zicmanis, P. Mekss. Imidazolium and pyridinium salts – solvents influencing the rate and direction of the Fries, Beckmann, and Claisen rearrangements. Chemistry of Heterocyclic Compounds. 2010-06, 46 (2): 158–169 [2022-01-16]. ISSN 0009-3122. doi:10.1007/s10593-010-0487-0 （英语）.
^ Javad Mokhtari, Mohammad R. Naimi-Jamal, Hamideh Hamzeali, Mohammad G. Dekamin, Gerd Kaupp. Kneading Ball-Milling and Stoichiometric Melts for the Quantitative Derivatization of Carbonyl Compounds with Gas-Solid Recovery. ChemSusChem. 2009-03-23, 2 (3): 248–254 [2022-01-16]. doi:10.1002/cssc.200800258 （英语）.

[1] Nidhi Jain, Anil Kumar, Shive M.S. Chauhan. Metalloporphyrin and heteropoly acid catalyzed oxidation of CNOH bonds in an ionic liquid: biomimetic models of nitric oxide synthase. Tetrahedron Letters. 2005-04, 46 (15): 2599–2602 [2022-01-16]. doi:10.1016/j.tetlet.2005.02.088 （英语）.

[2] Hajipour, A. R.; Zahmatkesh, S.; Ruoho, A. E. Methyltriphenylphosphonium peroxydisulfate (MTPPP): A mild and inexpensive reagent for the cleavage of oximes, phenylhydrazones and 2,4-dinitrophenylhydrazones to the corresponding carbonyl compounds under non-aqueous conditions. Journal of the Iranian Chemical Society, 2008. 5. pp S54~S58. ISSN 1735-207X.

[3] Henry Stephen, Benjamin Staskun. 204. A new mechanism for the Beckmann rearrangement of ketoximes. Journal of the Chemical Society (Resumed). 1956: 980 [2022-01-16]. ISSN 0368-1769. doi:10.1039/jr9560000980 （英语）.

[4] Marcin Szewczyk, Agata Bezłada, Jacek Mlynarski. Zinc-Catalyzed Enantioselective Hydrosilylation of Ketones and Imines under Solvent-Free Conditions. ChemCatChem. 2016-12-07, 8 (23): 3575–3579 [2022-01-16]. doi:10.1002/cctc.201601140 （英语）.

[5] S. Katkevica, A. Zicmanis, P. Mekss. Imidazolium and pyridinium salts – solvents influencing the rate and direction of the Fries, Beckmann, and Claisen rearrangements. Chemistry of Heterocyclic Compounds. 2010-06, 46 (2): 158–169 [2022-01-16]. ISSN 0009-3122. doi:10.1007/s10593-010-0487-0 （英语）.

[6] Javad Mokhtari, Mohammad R. Naimi-Jamal, Hamideh Hamzeali, Mohammad G. Dekamin, Gerd Kaupp. Kneading Ball-Milling and Stoichiometric Melts for the Quantitative Derivatization of Carbonyl Compounds with Gas-Solid Recovery. ChemSusChem. 2009-03-23, 2 (3): 248–254 [2022-01-16]. doi:10.1002/cssc.200800258 （英语）.

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苯乙酮肟

识别
CAS号	613-91-2 ^Y
性质
熔点	59—60 °C（332—333 K）^[1]
沸点	200—202 °C（473—475 K）^[2] 120—125 °C（393—398 K）（分解）^[3]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

苯乙酮肟

参考文献 编辑

参考文献编辑