1-氟丙烷
化合物
1-氟丙烷是一种有机化合物，化学式为C3H7F，是一种气体。它可以环丙烷和氟化氢钾在四氟化硅存在下反应得到。[3]它发生消除反应的能量为58.3 kcal·mol−1（激波管法测得）。[4]
| 1-氟丙烷 | |
|---|---|
| |
| 别名 | 氟代正丙烷 正丙基氟 PrF |
| 识别 | |
| CAS号 | 460-13-9 
|
| 性质 | |
| 化学式 | C3H7F |
| 摩尔质量 | 62.09 g·mol−1 |
| 密度 | 0.7818 g·cm−3[1] |
| 熔点 | −159 °C（114 K）[1] |
| 沸点 | −2.3 °C（270.8 K）（768 mmHg）[2] −2.5 °C（270.6 K）[1] |
| 溶解性（水） | 难溶 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献 编辑
- ^ 1.0 1.1 1.2 Aristid V. Grosse, Richard C. Wackher, Carl B. Linn. Physical Properties of the Alkyl Fluorides and a Comparison of the Alkyl Fluorides with the Other Alkyl Halides and with the Alkyls of the Elements of Period II.. The Journal of Physical Chemistry. 1940-03, 44 (3): 275–296 [2022-04-16]. ISSN 0092-7325. doi:10.1021/j150399a002. （原始内容存档于2021-06-28） （英语）.
- ^ Walter F. Edgell, L. Parts. Synthesis of Alkyl and Substituted Alkyl Fluorides from p-Toluenesulfonic Acid Esters. The Preparation of p-Toluenesulfonic Acid Esters of Lower Alcohols 1. Journal of the American Chemical Society. 1955-09, 77 (18): 4899–4902 [2022-04-16]. ISSN 0002-7863. doi:10.1021/ja01623a065 （英语）.
- ^ Masanori Tamura, Motonari Shibakami, Shigeru Kurosawa, Takashi Arimura, Akira Sekiya. Hydrofluorination of unsaturated compounds with solid potassium hydrogen fluoride in the presence of silicon tetrafluoride at room temperature. Journal of the Chemical Society, Chemical Communications. 1995, (18): 1891 [2022-04-16]. ISSN 0022-4936. doi:10.1039/c39950001891 （英语）.
- ^ P. Cadman, M. Day, A. W. Kirk, A. F. Trotman-Dickenson. Activation energies for the elimination of hydrogen fluoride from alkyl fluorides obtained by the activated molecule and competitive shock-tube techniques. Journal of the Chemical Society D: Chemical Communications. 1970, (4): 203 [2022-04-16]. ISSN 0577-6171. doi:10.1039/c29700000203 （英语）.