1-硝基萘
化合物
1-硝基萘是一种有机化合物，化学式为C10H7NO2。它可由萘的硝化反应制备，硝硫混酸是最常见的硝化试剂，[4][5]也有文献报道使用硝酸铋[6]、二氧化氮[7]、N-硝基糖精[8]等进行硝化反应。它可以被还原剂（如氢气[9]、硼氢化钠[10]、水合肼[11]等）还原为1-萘胺。
| 1-硝基萘 | |
|---|---|
| |
| 别名 | α-硝基萘 |
| 识别 | |
| CAS号 | 86-57-7 
|
| PubChem | 6849 |
| ChemSpider | 6588 |
| SMILES |
|
| Beilstein | 1867714 |
| UN编号 | 2538 |
| EINECS | 201-684-5 |
| ChEBI | 34104 |
| KEGG | C14040 |
| 性质 | |
| 化学式 | C10H7NO2 |
| 摩尔质量 | 173.17 g·mol−1 |
| 外观 | 浅黄色固体 |
| 密度 | 1.332 g·cm−3[1] |
| 熔点 | 59 °C（332 K）[2] |
| 溶解性（水） | 0.0035 g（25 °C）[3] |
| 危险性 | |
GHS危险性符号    
| |
| GHS提示词 | 危险 |
| H-术语 | H228, H301, H315, H319, H335, H351, H411 |
| P-术语 | P201, P202, P210, P240, P241, P261, P264, P270, P271, P273, P280, P281, P301+310, P302+352 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献 编辑
- ^ "Hazardous Substances Data Bank" data were obtained from the National Library of Medicine (US). Retrieved from SciFinder. [2020-12-28].
- ^ Badgujar, D. M.; Talwar, M. B.; Asthana, S. N.; Mahulikar, P. P. Environmentally benign synthesis of aromatic nitro compounds using silica supported inorganic nitrates. Journal of Scientific & Industrial Research, 2007. 66 (3): 250-251. ISSN: 0022-4456.
- ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-12-28].
- ^ Khabarov, Yu. G.; Veshnyakov, V. A.; Snigirev, I. A. Method for producing 1-nitronaphthalene. 2018. RU 2669774 C1.
- ^ Gerald Booth. Wiley-VCH Verlag GmbH & Co. KGaA , 编. Naphthalene Derivatives. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA. 2000-06-15 [2020-12-28]. ISBN 9783527306732. doi:10.1002/14356007.a17_009 （英语）.
- ^ Susanta Samajdar, Frederick F Becker, Bimal K Banik. Surface-mediated highly efficient regioselective nitration of aromatic compounds by bismuth nitrate. Tetrahedron Letters. 2000-10, 41 (42): 8017–8020 [2020-12-28]. doi:10.1016/S0040-4039(00)01397-6. （原始内容存档于2018-06-27） （英语）.
- ^ Kuiyi You, Zhongcang Zhou, Jian Jian, Renjie Deng, Pingle Liu, Qiuhong Ai, He’an Luo. A simple approach for preparation of dinitronaphthalene compounds from the nitration reaction of 1-nitronaphthalene with NO2 as nitration reagent. Research on Chemical Intermediates. 2015-11, 41 (11): 8307–8315 [2020-12-28]. ISSN 0922-6168. doi:10.1007/s11164-014-1893-1 （英语）.
- ^ Roxan Calvo, Kun Zhang, Alessandro Passera, Dmitry Katayev. Facile access to nitroarenes and nitroheteroarenes using N-nitrosaccharin. Nature Communications. 2019-12, 10 (1) [2020-12-28]. ISSN 2041-1723. PMC 6667458
. PMID 31363083. doi:10.1038/s41467-019-11419-y. （原始内容存档于2019-11-15） （英语）.
- ^ Huan Fu, Luna Ruan, Jianhua Liao, An Pei, Jun Liu, Li Zeng, Kai Yang, Lihua Zhu, Bing Hui Chen. PtNi/C bimetallic nanocatalyst with high catalytic performance and stability for 1-nitronaphthalene hydorgenation to 1-naphthylamine. Molecular Catalysis. 2020-10, 494: 111151 [2020-12-28]. doi:10.1016/j.mcat.2020.111151 （英语）.
- ^ Haydar Göksu, Nursefa Zengin, Hakan Burhan, Kemal Cellat, Fatih Şen. A Novel Hydrogenation of Nitroarene Compounds with Multi Wall Carbon Nanotube Supported Palladium/Copper Nanoparticles (PdCu@MWCNT NPs) in Aqueous Medium. Scientific Reports. 2020-12, 10 (1) [2020-12-28]. ISSN 2045-2322. PMC 7229225 . PMID 32415148. doi:10.1038/s41598-020-64988-0. （原始内容存档于2021-10-02） （英语）.
- ^ Upendra Sharma, Praveen Kumar Verma, Neeraj Kumar, Vishal Kumar, Manju Bala, Bikram Singh. Phosphane-Free Green Protocol for Selective Nitro Reduction with an Iron-Based Catalyst. Chemistry - A European Journal. 2011-05-16, 17 (21): 5903–5907 [2020-12-28]. doi:10.1002/chem.201003621 （英语）.
