2,3-二甲基-2-丁醇
化合物
2,3-二甲基-2-丁醇是一种有机化合物，化学式为C6H14O是六碳醇的同分异构体之一。它可由2,3-二甲基-2-丁烯的硼氢化-氧化反应制得。[7]甲基(三氟甲基)过氧化酮对2,3-二甲基丁烷的氧化也能得到该产物。[8]它和金属的二(三甲基硅基)氨基化物反应，生成金属的醇盐。[9]
| 2,3-二甲基-2-丁醇 | |
|---|---|
| |
| 英文名 | 2,3-Dimethyl-2-butanol |
| 识别 | |
| CAS号 | 594-60-5 
|
| 性质 | |
| 化学式 | C6H14O |
| 摩尔质量 | 102.17 g·mol−1 |
| 密度 | 0.8294 g·cm−3（20 °C）[1] 0.8155 g·cm−3（25 °C）[2] |
| 熔点 | −11.3 °C（261.8 K）[3] −14 °C（259 K）[4] |
| 沸点 | 118.4 °C（391.5 K）[4] 118.6 °C（391.8 K）[5] |
| 溶解性（水） | 2.3 g（25 °C）[6] |
| pKa | 15.24±0.29[6] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献 编辑
- ^ Levina, R. Ya.; Tantsyreva, T. I.; Fainzil'berg, A. A. Synthesis of hydrocarbons. XX. Synthesis of alkenes and alkanes with a quaternary carbon atom. Zhurnal Obshchei Khimii, 1952. 22: 571-577. ISSN: 0044-460X.
- ^ C. G. Overberger, M. B. Berenbaum. Azo Nitriles. VII. 1 Decomposition Products from 2,2'-Azo-bis-2,3,3-trimethylbutyronitrile. Products Obtained from a Substituted Neopentyl Radical. Journal of the American Chemical Society. 1952-07, 74 (13): 3293–3295 [2019-11-08]. ISSN 0002-7863. doi:10.1021/ja01133a022 （英语）.
- ^ M. GaŁązka, E. Juszyńska, P.M. Zieliński. General specific heat dependences on temperature in neohexanol and its isomers. Physica B: Condensed Matter. 2011-12, 406 (23): 4342–4349 [2019-11-08]. doi:10.1016/j.physb.2011.08.065. （原始内容存档于2018-06-09） （英语）.
- ^ 4.0 4.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2019-11-8]
- ^ Mohammad Goodarzi, Matheus P. Freitas. Predicting Boiling Points of Aliphatic Alcohols through Multivariate Image Analysis Applied to Quantitative Structure−Property Relationships. The Journal of Physical Chemistry A. 2008-11-06, 112 (44): 11263–11265 [2019-11-08]. ISSN 1089-5639. doi:10.1021/jp8059085 （英语）.
- ^ 6.0 6.1 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-11-8]
- ^ Herbert C. Brown, M. Mark Midland, George W. Kabalka. Organoboranes for synthesis. 5. Tetrahedron. 1986-01, 42 (20): 5523–5530 [2019-11-08]. doi:10.1016/S0040-4020(01)88155-2 （英语）.
- ^ Jack K. Crandall, Ruggero Curci, Lucia D'Accolti, Caterina Fusco. Methyl(trifluoro-methyl)dioxirane. John Wiley & Sons, Ltd. 2005-10-15 [2019-11-08]. ISBN 9780471936237. doi:10.1002/047084289x.rm267.pub2 （英语）.
- ^ Timo Hatanpää, Kaupo Kukli, Mikko Ritala, Markku Leskelä. Crystal structures and thermal properties of some rare earth alkoxides with tertiary alcohols: Possible precursors for atomic layer deposition of rare earth oxides. Journal of Thermal Analysis and Calorimetry. 2011-07, 105 (1): 61–71 [2019-11-08]. ISSN 1388-6150. doi:10.1007/s10973-011-1546-1 （英语）.