3-甲硫基丙醇
化合物
3-甲硫基丙醇是一种有机化合物，化学式为C4H10OS。它可由3-甲硫基丙醛的还原反应制得，[1]或以3-氯丙醇和甲硫醇钠为原料反应得到。[2]它可以被N-氟代二苯磺酰胺（NFSI）氧化为甲基羟丙基砜。[3]
| 3-甲硫基丙醇 | |
|---|---|
| |
| IUPAC名 3-methylsulfanylpropan-1-ol | |
| 识别 | |
| CAS号 | 505-10-2 
|
| PubChem | 10448 |
| ChemSpider | 10016 |
| SMILES |
|
| Beilstein | 1731208 |
| ChEBI | 49019 |
| 性质 | |
| 化学式 | C4H10OS |
| 摩尔质量 | 106.19 g·mol−1 |
| 危险性 | |
GHS危险性符号
| |
| GHS提示词 | 警告 |
| H-术语 | H315, H319, H335 |
| 相关物质 | |
| 相关化学品 | 1-(Methylthio)propane; Methional; Methionine; 1,3-Propanediol mono methyl ether; 4-(Methylsulfanyl)butanoic acid; 4-Thiapentanoic acid; |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献 编辑
- ^ Brandts, J. A. M.; Cavenaghi, C. V.; Gerlach, A.; Burk, M. J. Tethering technology: Anchored chiral and achiral homogeneous catalysts applied in enantio- and chemoselective hydrogenation reactions. Chimica Oggi, 2000. 18 (10): 47-49. ISSN 0392-839X.
- ^ Herbert C. Brown, Gary J. Lynch. Solvomercuration-demercuration. 9. Oxymercuration-demercuration of chloro-, epoxy-, and thiomethyl-substituted alkenes. The Journal of Organic Chemistry. 1981-02, 46 (5): 930–939 [2022-03-29]. ISSN 0022-3263. doi:10.1021/jo00318a019. （原始内容存档于2022-03-29） （英语）.
- ^ Xiaobo Xu, Leyu Yan, Shengqiang Wang, Panpan Wang, A-Xiu Yang, Xiaolong Li, Hao Lu, Zhong-Yan Cao. Selective synthesis of sulfoxides and sulfones via controllable oxidation of sulfides with N -fluorobenzenesulfonimide. Organic & Biomolecular Chemistry. 2021, 19 (40): 8691–8695 [2022-03-29]. ISSN 1477-0520. doi:10.1039/D1OB01632F （英语）.