三(氰乙基)膦

化合物

三(氰乙基)膦是一種有機磷化合物,化學式為P(CH2CH2CN)3。它是白色固體,在空氣中穩定,這一性質在三烷基膦中並不常見。它可由丙烯腈磷化氫的反應製備。[2]四羥甲基硫酸鏻[3]或四羥甲基氯化鏻[4]也可作為原料反應。它在乙酸中被過氧化氫氧化,生成三(氰乙基)氧化膦。[3]它也可作為配體與金屬鹽形成配合物。[5][6]

三(氰乙基)膦
識別
CAS號 4023-53-4  checkY
PubChem 77639
ChemSpider 70043
SMILES
 
  • C(CP(CCC#N)CCC#N)C#N
性質
化學式 C9H12N3P
摩爾質量 193.19 g·mol−1
外觀 白色固體
熔點 97 °C(370 K)[1]
危險性
GHS危險性符號
《全球化學品統一分類和標籤制度》(簡稱「GHS」)中有毒物質的標籤圖案《全球化學品統一分類和標籤制度》(簡稱「GHS」)中有害物質的標籤圖案《全球化學品統一分類和標籤制度》(簡稱「GHS」)中對人體有害物質的標籤圖案
GHS提示詞 危險
H-術語 H301, H302, H311, H315, H319, H330, H331, H335, H350
P-術語 P201, P202, P260, P261, P264, P270, P271, P280, P281, P284, P301+310, P301+312, P302+352, P304+340
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

編輯
  1. ^ Valetdinov, R. K.; Kuznetsov, E. V.; Komissarova, S. L. Reaction of hydroxymethyl derivatives of hydrogen phosphide with acrylic acid nitrile(俄文). Zhurnal Obshchei Khimii, 1969. 39 (8): 1744-1746. ISSN: 0044-460X.
  2. ^ Trofimov, Boris A.; Arbuzova, Svetlana N.; Gusarova, Nina K. Phosphine in the synthesis of organophosphorus compounds. Russian Chemical Reviews. 1999, 68. doi:10.1070/RC1999v068n03ABEH000464. 
  3. ^ 3.0 3.1 Zhi-Wei Tan, Jian Sun, Min Zhang, Jin-Jun Qiu, Si-Qian Hu, Cheng-Mei Liu. Phosphorus-containing polymers from THPS. II: synthesis and property of phosphorus-containing hyperbranched aromatic-aliphatic polyamides. Designed Monomers and Polymers. 2015-04-03, 18 (3): 222–231 [2020-01-18]. ISSN 1568-5551. doi:10.1080/15685551.2014.999461. (原始內容存檔於2020-02-04) (英語). 
  4. ^ Kevin Bruyninckx, Koen J.A. Jansens, Bart Goderis, Jan A. Delcour, Mario Smet. Removal of disulfide cross-links from wheat gluten and the effect thereof on the mechanical properties of rigid gluten bioplastic. European Polymer Journal. 2015-07, 68: 573–584 [2020-01-18]. doi:10.1016/j.eurpolymj.2015.03.047. (原始內容存檔於2020-02-04) (英語). 
  5. ^ Ross J. Davidson, Eric W. Ainscough, Andrew M. Brodie, Graham H. Freeman, Geoffrey B. Jameson. Structural studies on tris(2-cyanoethyl)phosphine complexes of Cu(I): The sensitivity of the secondary nitrile coordination to the nature of the anion. Polyhedron. 2014-09, 79: 330–337 [2020-01-18]. doi:10.1016/j.poly.2014.05.034. (原始內容存檔於2020-02-04) (英語). 
  6. ^ Valentina Gandin, Marina Porchia, Francesco Tisato, Alessandro Zanella, Emilia Severin, Alessandro Dolmella, Cristina Marzano. Novel Mixed-Ligand Copper(I) Complexes: Role of Diimine Ligands on Cytotoxicity and Genotoxicity. Journal of Medicinal Chemistry. 2013-09-26, 56 (18): 7416–7430 [2020-01-18]. ISSN 0022-2623. doi:10.1021/jm400965m. (原始內容存檔於2020-02-04) (英語).