高氯酸铽是一种无机化合物,化学式为Tb(ClO4)3,它可通过七氧化四铽高氯酸反应得到。[3]它可以和丙氨酸形成配合物[Tb2(C3H7NO2)4(H2O)8](ClO4)6[4]它可用于合成含铽的金属有机框架材料[5][6]

高氯酸铽

识别
CAS号 14014-09-6(无水)  checkY
80398-56-7(六水)  checkY
性质
化学式 Cl3O12Tb
摩尔质量 457.28 g·mol−1
外观 浅粉色晶体(六水)[1]
密度 2.21 g/cm3(六水)[2]
溶解性 可溶于水(无水、六水)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ 1.0 1.1 Jane E. Macintyre. Dictionary of Inorganic Compounds. CRC Press. 23 July 1992: 2930– [2023-03-15]. ISBN 978-0-412-30120-9. (原始内容存档于2023-03-15). 
  2. ^ Glaser J. Crystal structures of the isomorphous perchlorate hexahydrates of some trivalent metal ions (M= La, Tb, Er, Tl). Acta Chemica Scandinavica A. 1981. 35. 639-644
  3. ^ Jintai Lin, Yuhui Zheng, Qianming Wang. Conversion of Lewis acid-base interaction into readable emission outputs by novel terbium hybrid nanosphere. Dyes and Pigments. 2015-01, 112: 239–244 [2023-03-15]. doi:10.1016/j.dyepig.2014.07.014 (英语). 
  4. ^ Musa E. Mohamed, Deepak Chopra, K. N. Venugopal, Thavendran Govender, Hendrik G. Kruger, Glenn E. M. Maguire. Tetrakis-μ- L -alanine-κ 8 O : O ′-bis[tetraaquaterbium(III)] hexaperchlorate. Acta Crystallographica Section E Structure Reports Online. 2010-02-15, 66 (2): m193–m194 [2023-03-15]. ISSN 1600-5368. doi:10.1107/S1600536810002448. (原始内容存档于2023-05-31). 
  5. ^ Wan-Zhen Qiao, Hang Xu, Peng Cheng, Bin Zhao. 3d-4f Heterometal–Organic Frameworks for Efficient Capture and Conversion of CO 2. Crystal Growth & Design. 2017-06-07, 17 (6): 3128–3133 [2023-03-15]. ISSN 1528-7483. doi:10.1021/acs.cgd.7b00063. (原始内容存档于2023-05-31) (英语). 
  6. ^ E. Bartolomé, J. Bartolomé, A. Arauzo, J. Luzón, L. Badía, R. Cases, F. Luis, S. Melnic, D. Prodius, S. Shova, C. Turta. Antiferromagnetic single-chain magnet slow relaxation in the {Tb(α-fur) 3 } n polymer with non-Kramers ions. Journal of Materials Chemistry C. 2016, 4 (22): 5038–5050 [2023-03-15]. ISSN 2050-7526. doi:10.1039/C6TC00919K (英语).