硝酸氙是一種使二氟化氙無水硝酸反應製得的過渡化合物。 儘管二硝酸氙 (Xe(NO3)2) 尚未被分離,它的一硝酸鹽:硝酸氟化氙(XeFNO3)已經進行了研究。

製備

編輯

嘗試生產二硝酸氙的方法: [1]

XeF2 + 2HNO3 → Xe(NO3)2 + 2HF[2][3]

這個反應取得了紅棕色的固體,在23 °C 下變藍,持續很短時間,然後猛烈分解。[2]

這個分解反應是:

Xe(NO3)2 → Xe + O2NOONO2 (不穩定的氮過氧化物)

但是,確實存在混合硝酸鹽FXeONO2[1] 這個化合物被稱為一硝酸氟化氙[4] 或氟硝酸化氙。[5]


參考資料

編輯
  1. ^ 1.0 1.1 Moran, Matthew D. Synthesis and Structural Characterization of new Xenon(II) Compounds and the Use of a Xenon(II) Cation as an Oxidant for the Preparation of Halogenated Hydrocarbons (PDF). McMaster University. 2007: 42, 99–145 [4 Oct 2014]. (原始內容存檔 (PDF)於2016-03-03). 
  2. ^ 2.0 2.1 Eisenberg, Max; Darryl D. DesMarteau. The reaction of xenon difluoride with some strong oxy-acids. Inorganic and Nuclear Chemistry Letters. 1970, 6 (1): 29–34. ISSN 0020-1650. doi:10.1016/0020-1650(70)80279-3. 
  3. ^ Zefirov, N. S; Gakh, A. A.; Zhdankin, V. V.; Stang, P. J. Interaction of Fluoroxenonium Triflate, Fluorosulfate, and Νitrate with Alkenes. Stereochemical Evidence for the Electrophilic Noble Gas Cation Addition to the Carbon-Carbon Double Bond. J. Org. Chem. 1991, 56: 1416–1418. doi:10.1021/jo00004a015. 
  4. ^ Atta-ur-Rahman. Advances in Organic Synthesis: Modern Organofluorine Chemistry-Synthetic Aspects. Bentham Science Publishers. 2006-01-01: 78 [5 October 2014]. ISBN 9781608051984. 
  5. ^ Moran, Matthew D.; David S. Brock; Hélène P. A. Mercier; Gary J. Schrobilgen. Xe3OF3+, a Precursor to a Noble-Gas Nitrate; Syntheses and Structural Characterizations of FXeONO2, XeF2·HNO3, and XeF2·N2O4. Journal of the American Chemical Society. 2010, 132 (39): 13823–13839. ISSN 0002-7863. PMID 20843046. doi:10.1021/ja105618w.