三氟甲磺酸铀酰

三氟甲磺酸铀酰是一种无机化合物,化学式为UO2(CF3SO3)2。它可由三氧化铀三氟甲磺酸三氟甲磺酸酐反应制得。[1]它和双(环辛四烯)合铀吡啶中回流反应,可以得到[U6O8(CF3SO3)8(C5H5N)8]。[2]它和三甲基碘硅烷反应,可以得到碘化铀酰[3]

三氟甲磺酸铀酰
识别
CAS号 168915-05-7  checkY
性质
化学式 C2F6O8S2U
摩尔质量 568.17 g·mol−1
外观 浅黄色粉末(无水)
亮黄色粉末(水合)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献 编辑

  1. ^ 1.0 1.1 Berthet, Jean Claude; Lance, Monique; Nierlich, Martine; Ephritikhine, Michel. Simple Preparations of the Anhydrous and Solvent-Free Uranyl and Cerium(IV) Triflates UO2(OTf)2 and Ce(OTf)4 − Crystal Structures of UO2(OTf)2(py)3 and [{UO2(py)4}2(μ-O)][OTf]2. European Journal of Inorganic Chemistry (Wiley). 2000, 2000 (9): 1969–1973. ISSN 1434-1948. doi:10.1002/1099-0682(200009)2000:9<1969::aid-ejic1969>3.0.co;2-0. 
  2. ^ Berthet, Jean-Claude; Thuéry, Pierre; Ephritikhine, Michel. Formation of Uranium(IV) Oxide Clusters from Uranocene [U(η8-C8H8)2] and Uranyl [UO2X2] Compounds. Inorganic Chemistry (American Chemical Society (ACS)). 2010-07-26, 49 (17): 8173–8177. ISSN 0020-1669. doi:10.1021/ic101310z. 
  3. ^ Berthet, Jean-Claude; Nierlich, Martine; Ephritikhine, Michel. Synthesis of the stable UO2I2, the last of the uranyl dihalides. X-Ray crystal structure of [UO2I2(py)3]. Chemical Communications (Royal Society of Chemistry (RSC)). 2004, (7): 870. ISSN 1359-7345. doi:10.1039/b400717d.