乙酰丙酮钕
乙酰丙酮钕是一种配位化合物，化学式为Nd(C5H7O2)3，或简写为Nd(acac)3，它的不稳定常数（logYn）分别为2.89、4.15和5.26（对应n=1, 2, 3）。[2]它可由三烷氧基钕和乙酰丙酮反应制得，[3]或通过金属钕在乙酰丙酮中电解得到。[4]它的二水合物和羰基铼配合物Re(CO)3X(4,4'-bipy)（X=Cl, Br）反应，可以得到Re(CO)3X(4,4'-bipy)Nd(acac)3。[5]
| 乙酰丙酮钕 | |
|---|---|
neodymium.png)
| |
| 英文名 | Neodymium acetylacetonate |
| 识别 | |
| CAS号 | 14589-38-9 
|
| 性质 | |
| 化学式 | C15H21NdO6 |
| 摩尔质量 | 441.57 g·mol−1 |
| 外观 | 粉色粉末[1] |
| 熔点 | 150 °C（423 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献 编辑
- ^ 1.0 1.1 Pierson, H.O. Handbook of Chemical Vapor Deposition: Principles, Technology and Applications. Materials Science and Process Technology. Elsevier Science. 1999: 92 [2021-09-16]. ISBN 978-0-8155-1743-6. （原始内容存档于2021-10-17）.
- ^ N.K. Dutt, P. Banyopadhyay. Chemistry of the lanthanons—XIII. Journal of Inorganic and Nuclear Chemistry. 1964-05, 26 (5): 729–736 [2021-09-20]. doi:10.1016/0022-1902(64)80316-X. （原始内容存档于2018-06-24） （英语）.
- ^ Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates（俄文）. Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.
- ^ Panyushkin, V. T.; Frolov, V. Yu.; Zelenov, V. I. Electrochemical synthesis of rare-earth metal acetylacetonates. Russian Journal of General Chemistry (Translation of Zhurnal Obshchei Khimii), 2001. 71 (8): 1318.
- ^ Shapoval, A. N.; Bobukhov, D. V.; Rusakova, N. V.; Shtemenko, A. V.; Snurnikova, O. V.; Korovin, Yu. V. Synthesis and spectral-luminescent properties of mono- (Re+) and heteronuclear (Re+-Ln3+) tricarbonyl-halo complexes（俄文）. Ukrainskii Khimicheskii Zhurnal (Russian Edition), 2007. 73 (9-10): 34-36. ISSN 0041-6045.