五唑化𨥙
五唑化𨥙是一种无机化合物，化学式为N2H5N5，具有吸湿性。[3]它可由五唑化镁的水合物（[Mg(H2O)6][(N5)2(H2O)4]）和硫酸𨥙（(NH3NH2)2SO4）反应制得。[1]它和吡嗪-1,4-二氧化物形成共晶，可以提高它的稳定性。[4]
| 五唑化𨥙 | |
|---|---|
| 识别 | |
| CAS号 | 2408152-24-7 
|
| PubChem | 168340102 |
| SMILES |
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| 性质 | |
| 化学式 | H5N7 |
| 摩尔质量 | 103.09 g·mol−1 |
| 外观 | 白色固体[1] |
| 密度 | 1.620 g·cm-3[1] |
| 熔点 | 85.3 °C（分解）[1] 99.6 °C（分解）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献 编辑
- ^ 1.0 1.1 1.2 1.3 Yang, Chen; Zhang, Chong; Zheng, Zhansheng; Jiang, Chao; Luo, Jun; Du, Yang; Hu, Bingcheng; Sun, Chengguo; Christe, Karl O. Synthesis and Characterization of cyclo-Pentazolate Salts of NH4+, NH3OH+, N2H5+, C(NH2)3+, and N(CH3)4+. Journal of the American Chemical Society (American Chemical Society (ACS)). 2018-11-05, 140 (48): 16488–16494. ISSN 0002-7863. doi:10.1021/jacs.8b05106.
- ^ Xu, Yuangang; Tian, Lili; Li, Dongxue; Wang, Pengcheng; Lu, Ming. A series of energetic cyclo-pentazolate salts: rapid synthesis, characterization, and promising performance. Journal of Materials Chemistry A (Royal Society of Chemistry (RSC)). 2019, 7 (20): 12468–12479. ISSN 2050-7488. doi:10.1039/c9ta01077g.
- ^ Li, Tian‐cheng; Lu, Tong‐jie; Lei, Qing; Xu, Yuan‐gang; Lin, Qiu‐han; Lu, Ming; Lu, Yan‐hua; Wang, Peng‐cheng. Thermal Decomposition Kinetics of Potential Solid Propellant Combustion Catalysts Fe(II), Zn(II), Hydroxylammonium, and Hydrazinium Pentazolates. Propellants, Explosives, Pyrotechnics (Wiley). 2021-08-21, 47 (1). ISSN 0721-3115. doi:10.1002/prep.202100140.
- ^ Zhou, Jianxin; Li, Xinyi; Hou, Tianyang; Xu, Ze; Wang, Pengcheng; Lu, Ming; Xu, Yuangang. Improving the stability of hydrazinium pentazolate through cocrystallization. CrystEngComm (Royal Society of Chemistry (RSC)). 2023, 25 (14): 2027–2031. ISSN 1466-8033. doi:10.1039/d2ce01707e.