六氟铋酸二氟合氯
六氟铋酸二氟合氯是一种无机化合物，化学式为ClF2BiF6，它与BiF2SbF6及ClF2TaF6同构。[1]它在−60 °C时为三斜晶系晶体，空间群P1。[2]它可由五氟化铋和三氟化氯反应得到。[3]它受热分解，产物为ClF3、ClF2Bi2F11和BiF5。[4]
| 六氟铋酸二氟合氯 | |
|---|---|
| |
| 英文名 | Difluorochlorine(1+) hexafluorobismuthate(1-) |
| 识别 | |
| CAS号 | 38785-48-7 
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| SMILES |
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| 性质 | |
| 化学式 | ClF2BiF6 |
| 摩尔质量 | 396.42 g·mol⁻¹ |
| 外观 | 固体 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献 编辑
- ^ Kuz'min, A. I.; Sukhoverkhov, V. F.; Sharabarin, A. V. Nuclear quadrupole resonance study of bismuth pentafluoride and its complex with chlorine trifluoride. Zhurnal Neorganicheskoi Khimii, 1981. 26 (3): 821-823. ISSN: 0044-457X.
- ^ Ellern, A. M.; Antipin, M. Yu.; Sharabarin, A. V.; Struchkov, Yu. T. Crystal and molecular structure of difluorochlorine(1+) hexafluorobismuthate(1-). Zhurnal Neorganicheskoi Khimii, 1992. 37 (1): 86-88. ISSN: 0044-457X.
- ^ Dale, James W. Difluorochlorinium hexafluorobismuthate. 1972. US 3663183 A.
- ^ Sukhoverkhov, V. F.; Sharabarin, A. V. Synthesis and study of bismuth pentafluoride and some of its complexes. Zhurnal Neorganicheskoi Khimii, 1983. 28 (3): 629-633. ISSN: 0044-457X.