六氟铋酸二氟合氯

六氟铋酸二氟合氯是一种无机化合物,化学式为ClF2BiF6,它与BiF2SbF6及ClF2TaF6同构。[1]它在−60 °C时为三斜晶系晶体,空间群P1[2]它可由五氟化铋三氟化氯反应得到。[3]它受热分解,产物为ClF3、ClF2Bi2F11和BiF5[4]

六氟铋酸二氟合氯
英文名 Difluorochlorine(1+) hexafluorobismuthate(1-)
识别
CAS号 38785-48-7  checkY
SMILES
 
  • F[Cl+]F.F[Bi-](F)(F)(F)(F)F
性质
化学式 ClF2BiF6
摩尔质量 396.42 g·mol⁻¹
外观 固体
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Kuz'min, A. I.; Sukhoverkhov, V. F.; Sharabarin, A. V. Nuclear quadrupole resonance study of bismuth pentafluoride and its complex with chlorine trifluoride. Zhurnal Neorganicheskoi Khimii, 1981. 26 (3): 821-823. ISSN: 0044-457X.
  2. ^ Ellern, A. M.; Antipin, M. Yu.; Sharabarin, A. V.; Struchkov, Yu. T. Crystal and molecular structure of difluorochlorine(1+) hexafluorobismuthate(1-). Zhurnal Neorganicheskoi Khimii, 1992. 37 (1): 86-88. ISSN: 0044-457X.
  3. ^ Dale, James W. Difluorochlorinium hexafluorobismuthate. 1972. US 3663183 A.
  4. ^ Sukhoverkhov, V. F.; Sharabarin, A. V. Synthesis and study of bismuth pentafluoride and some of its complexes. Zhurnal Neorganicheskoi Khimii, 1983. 28 (3): 629-633. ISSN: 0044-457X.