四异丙基甲烷

四异丙基甲烷是一种有机化合物,化学式为C13H28,它是甲烷的四个氢全部被异丙基取代的产物。它可由四环丙基甲烷氢气二氧化铂催化下于乙酸中反应制得。[1]在−110 °C下,它在溶液中存在两种构象;[2]在晶体中,它具有C2v对称性[3]

四异丙基甲烷
识别
CAS号 332105-02-9  checkY
PubChem 19821547
性质
化学式 C13H28
摩尔质量 184.36 g·mol−1
外观 无色固体[1]
熔点 74—76 °C(347—349 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ 1.0 1.1 1.2 Sergei I. Kozhushkov, Rafael R. Kostikov, Alexander P. Molchanov, Roland Boese, Jordi Benet-Buchholz, Peter R. Schreiner, Christopher Rinderspacher, Ion Ghiviriga, Armin de Meijere. Tetracyclopropylmethane: A Unique Hydrocarbon with S4 Symmetry. Angewandte Chemie International Edition. 2001-01-05, 40 (1): 180–183 [2023-01-12]. doi:10.1002/1521-3773(20010105)40:13.0.CO;2-K (英语). 
  2. ^ J. Edgar Anderson, Armin de Meijere, Sergei I. Kozhushkov, Lodovico Lunazzi, Andrea Mazzanti. Conformational Dynamics of Tetraisopropylmethane and of Tetracyclopropylmethane 1. Journal of the American Chemical Society. 2002-06-01, 124 (23): 6706–6713 [2023-01-12]. ISSN 0002-7863. doi:10.1021/ja017526j. (原始内容存档于2023-01-12) (英语). 
  3. ^ Armin de Meijere, S. I. Kozhushkov, A. A. Fokin, I. Emme, S. Redlich, P. R. Schreiner. New structurally interesting cyclopropane derivatives. A world of wonders and surprises. Pure and Applied Chemistry. 2003-01-01, 75 (5): 549–562 [2023-01-12]. ISSN 1365-3075. doi:10.1351/pac200375050549. (原始内容存档于2023-01-14) (英语).