正十一胺
化合物
正十一胺是一种有机化合物，化学式为C11H25N。它可由正十一腈[1]或1-硝基十一烷[2]的还原反应制得。十二烷酰胺和次氯酸钠反应，也能得到正十一胺。[3]它和氟硼酸反应，生成氟硼酸正十一铵（C11H23NH3BF4）[4]，和盐酸发生类似反应，生成相应的盐酸盐[5]。它可以发生甲基化反应，生成N,N-二甲基正十一胺。[6]
| 正十一胺 | |
|---|---|
| |
| 别名 | 1-十一胺 1-氨基十一烷 十一烷胺 |
| 识别 | |
| CAS号 | 7307-55-3 
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| SMILES |
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| 性质 | |
| 化学式 | C11H25N |
| 摩尔质量 | 171.32 g·mol−1 |
| 熔点 | 17 °C（290 K） |
| 沸点 | 242 °C（515 K） |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Rosa Adam, Elisabetta Alberico, Wolfgang Baumann, Hans-Joachim Drexler, Ralf Jackstell, Henrik Junge, Matthias Beller. NNP-Type Pincer Imidazolylphosphine Ruthenium Complexes: Efficient Base-Free Hydrogenation of Aromatic and Aliphatic Nitriles under Mild Conditions. Chemistry - A European Journal. 2016-03-24, 22 (14): 4991–5002 [2021-01-14]. doi:10.1002/chem.201504709 （英语）.
- ^ Petros L. Gkizis, Manolis Stratakis, Ioannis N. Lykakis. Catalytic activation of hydrazine hydrate by gold nanoparticles: Chemoselective reduction of nitro compounds into amines. Catalysis Communications. 2013-06, 36: 48–51 [2021-01-14]. doi:10.1016/j.catcom.2013.02.024. （原始内容存档于2020-10-01） （英语）.
- ^ Dhananjay S. Rane, Man M. Sharma. New strategies for the Hofmann reaction. Journal of Chemical Technology AND Biotechnology. 1994-03, 59 (3): 271–277 [2021-01-14]. ISSN 0268-2575. doi:10.1002/jctb.280590310 （英语）.
- ^ Giorgio Olivo, Giulio Farinelli, Alessia Barbieri, Osvaldo Lanzalunga, Stefano Di Stefano, Miquel Costas. Supramolecular Recognition Allows Remote, Site-Selective C−H Oxidation of Methylenic Sites in Linear Amines. Angewandte Chemie International Edition. 2017-12-18, 56 (51): 16347–16351 [2021-01-14]. doi:10.1002/anie.201709280 （英语）.
- ^ Limanov, V. E.; Ivanov, S. B.; Sukiasyan, A. N.; Skvortsova, E. K. Synthesis and antimicrobial activity of compounds obtained from higher alkylamines. Khimiko-Farmatsevticheskii Zhurnal, 1981. 15 (6): 35-39. ISSN: 0023-1134.
- ^ Md.A.R. Jamil, Abeda S. Touchy, Md. Nurnobi Rashed, Kah Wei Ting, S.M.A. Hakim Siddiki, Takashi Toyao, Zen Maeno, Ken-ichi Shimizu. N-Methylation of amines and nitroarenes with methanol using heterogeneous platinum catalysts. Journal of Catalysis. 2019-03, 371: 47–56 [2021-01-14]. doi:10.1016/j.jcat.2019.01.027 （英语）.