环辛炔

化合物

环辛炔是一种有机化合物,化学式为C8H12。它可以1-溴环辛烯和二异丙氨基钠反应制得。[2]它和1-叠氮基金刚烷在乙腈中反应,可以得到1-金刚烷基-1H-环辛烷并三唑[3]它可以和卤化亚铜形成配合物(C8H12)2Cu2X2(X=Cl, Br, I)。[4]

环辛炔
识别
CAS号 1781-78-8  checkY
性质
化学式 C8H12
摩尔质量 108.18 g·mol−1
沸点 80 °C(60 torr)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Dehmlow, Eckehard V.; Lissel, Manfred. Uses of phase-transfer catalysis. 14. Preparation of alkynes from alkyl halides with solid potassium tert-butoxide and crown ether. Liebigs Annalen der Chemie, 1980. 1: 1-13. ISSN 0170-2041.
  2. ^ Yun Ma, Russell F. Algera, David B. Collum. Sodium Diisopropylamide in N,N -Dimethylethylamine: Reactivity, Selectivity, and Synthetic Utility. The Journal of Organic Chemistry. 2016-11-18, 81 (22): 11312–11315 [2022-04-06]. ISSN 0022-3263. PMC 5242189 . PMID 27768310. doi:10.1021/acs.joc.6b02287. (原始内容存档于2022-04-06) (英语). 
  3. ^ Matthias Müller, Cäcilia Maichle-Mössmer, Holger F. Bettinger. Boryl Azides in 1,3-Dipolar Cycloadditions. The Journal of Organic Chemistry. 2014-06-20, 79 (12): 5478–5483 [2022-04-06]. ISSN 0022-3263. doi:10.1021/jo500549m (英语). 
  4. ^ Gunther Gröger, Ulrich Behrens, Falk Olbrich. Monomeric and Dimeric Cyclooctyne-Stabilized Complexes of Copper(I) 1. Organometallics. 2000-08-01, 19 (17): 3354–3360 [2022-04-06]. ISSN 0276-7333. doi:10.1021/om000079g. (原始内容存档于2022-04-06) (英语).