甲酸镓是一种化合物,化学式为Ga(HCOO)3,它可溶于水,可以分解为氧化镓[1]它可以氢化镓或氨基镓为原料反应得到。[2]氢氧化镓甲酸的反应只能得到碱式盐Ga(O2CH)(OH)2[3]碳酸镓和甲酸反应,得到的是甲酸镓二氧化碳包合物Ga(HCOO)3·0.75CO2·0.25H2O·0.25HCOOH。[4][5]

甲酸镓

英文名 gallium formate
识别
CAS号 16843-87-1  checkY
SMILES
 
  • O=C[O-].[Ga+3].[O-]C=O.[O-]C=O
性质
化学式 C3H3GaO6
摩尔质量 204.78 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ V Yu Davydov, R E Dunin-Borkovski, V G Golubev, J L Hutchison, N F Kartenko, D A Kurdyukov, A B Pevtsov, N V Sharenkova, J Sloan, L M Sorokin. Fabrication and structure of an opal-gallium nitride nanocomposite. Semiconductor Science and Technology. 2001-02-01, 16 (2): L5–L7 [2020-07-09]. ISSN 0268-1242. doi:10.1088/0268-1242/16/2/101. 
  2. ^ Philip P. Power; Susan M. Kauzlarich. IV.B.5l Chemical Hydrogen Storage using Ultra-High Surface AreaMain Group Materials and The Development of Efficient Amine-BoraneRegeneration Cycles. FY 2007 Annual Progress Report.
  3. ^ K. Wade, A. J. Banister. The Chemistry of Aluminium, Gallium, Indium and Thallium: Comprehensive Inorganic Chemistry. Elsevier. 2016. pp 1106. ISBN 9781483153223.
  4. ^ Yun-Qi Tian, Yu-Ming Zhao, Hai-Jun Xu, Cheng-Yu Chi. CO 2 Template Synthesis of Metal Formates with a ReO3 Net. Inorganic Chemistry. 2007-03, 46 (5): 1612–1616 [2020-07-09]. ISSN 0020-1669. doi:10.1021/ic0617240 (英语). 
  5. ^ 田运齐. 立方甲酸铝和甲酸镓及制备方法. 2007. CN 101033186A.