苯基三氯化碲
苯基三氯化碲是一种有机化合物，化学式为C6H5TeCl3。它可由氯化苯基汞[3]、四苯基锡[4]或三甲基硼[5]和四氯化碲反应得到。它是三斜晶系晶体，空间群P1，通过氯桥连接形成二聚结构。[1]
| 苯基三氯化碲 | |
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| 识别 | |
| CAS号 | 29510-67-6 
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| 性质 | |
| 化学式 | C6H5Cl3Te |
| 摩尔质量 | 311.06 g·mol−1 |
| 密度 | 2.33 g·cm−3[1] |
| 熔点 | 215—215 °C（488—488 K）（分解）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献 编辑
- ^ 1.0 1.1 F. W. B. Einstein, T. Jones. Structure of phenyltellurium trichloride. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 1982-02-15, 38 (2): 617–619 [2021-06-03]. doi:10.1107/S0567740882003549. （原始内容存档于2018-06-02）.
- ^ Petragnani, Nicolo; Campos, Marcello de Moura. Organic tellurium derivatives. VI. Reaction of elementary tellurium with phenylmagnesium bromide and phenyllithium. Chemische Berichte, 1963. 96: 249-252. ISSN: 0009-2940.
- ^ Rosenfeld, Mosche Nathan. Studies Related to the Synthesis of Tetracycline [Dissertation]. 1976. Department of Chemistry Imperial College, South Kensington London. CAN157: 519734.
- ^ Singhal, Kiran. Electrophilic cleavage of tin-alicyclic and tin-aryl bonds involving the synthesis of cyclohexyl-tin, -tellurium and -antimony compounds. Part I. Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 1993. 32A (6): 542-544. ISSN: 0376-4710.
- ^ David P. Rainville, Ralph A. Zingaro. The reactions of selenium tetrachloride and tellurium tetrachloride with some trivalent aryl organometallic halides. Journal of Organometallic Chemistry. 1980-05, 190 (3): 277–288 [2021-06-03]. doi:10.1016/S0022-328X(00)83985-6. （原始内容存档于2018-06-08） （英语）.