苯胺高氯酸盐

苯胺高氯酸盐苯胺高氯酸形成的盐类,化学式为C6H5NH3ClO4。它可由饱和苯胺的水溶液和高氯酸按1:1化学计量比反应得到,其晶体属正交晶系P212121空间群[3]它在四氢呋喃中的pKa为7.97,在二甲基亚砜中的pKa为3.6。[4]

苯胺高氯酸盐
别名 高氯酸苯铵
AP
识别
CAS号 14796-11-3  checkY
性质
化学式 C6H8ClNO4
摩尔质量 193.59 g·mol−1
外观 无色晶体,放置时变为棕色
熔点 250 °C(或265 °C[1])(爆炸)[2]
溶解性 易溶
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ G. Singh, I. P. S. Kapoor, S. M. Mannan. Studies on energetic compounds: IV. Thermal explosion of ring-substituted arylammonium perchlorates. Journal of Thermal Analysis. 1996-06, 46 (6): 1751–1761 [2021-06-26]. ISSN 0368-4466. doi:10.1007/BF01980780 (英语). 
  2. ^ Spallino, R. Perchlorates of aromatic amines. Annali di Chimica Applicata, 1914. 1: 435-440. ISSN: 0365-1037.
  3. ^ P. Vivek, A. Suvitha, P. Murugakoothan. Growth, spectral, anisotropic, second and third order nonlinear optical studies on potential nonlinear optical crystal anilinium perchlorate (AP) for NLO device fabrications. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2015-01, 134: 517–525 [2021-06-26]. doi:10.1016/j.saa.2014.05.051 (英语). 
  4. ^ Gemma Garrido, Martí Rosés, Clara Ràfols, Elisabeth Bosch. Acidity of Several Anilinium Derivatives in Pure Tetrahydrofuran. Journal of Solution Chemistry. 2008-05, 37 (5): 689–700 [2021-06-26]. ISSN 0095-9782. doi:10.1007/s10953-008-9262-6 (英语).