草酸釤是釤的草酸盐，化学式为Sm2(C2O4)3，其水合物可由硝酸钐和草酸在水溶液中反应得到：
- 2 Sm(NO3)3 + 3 H2C2O4 → Sm2(C2O4)3 + 6 HNO3
它的十水合物受热分解得到无水物，继续加热得到氧化釤。[1]它和盐酸反应得到Sm(C2O4)Cl·3H2O。[2]
参考文献
编辑
- ^ Wendlandt, W. W. Thermal Decomposition of Rare Earth Metal Oxalates. Analytical Chemistry. 1959, 31 (3): 408–410. ISSN 0003-2700. doi:10.1021/ac60147a024.
- ^ Moebius, R.; Matthes, F. The exchange of oxalate ions for chloride ions of the oxalate hydrates of the rare earths and yttrium. Zeitschrift fuer Chemie, 1964. 4 (6): 234-235. ISSN: 0044-2402.
