高锰酸四氨合铜(II)

高锰酸四氨合铜(II)
识别
CAS号	39729-79-8
性质
化学式	[Cu(NH3)4](MnO4)2
摩尔质量	369.53 g·mol⁻¹
外观	暗紫色晶体
密度	2.33 g·cm−3
沸点	283 K（缓慢分解）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

高锰酸四氨合铜(II)是一种无机化合物，化学式为[Cu(NH₃)₄](MnO₄)₂。它可由硫酸铜、氨水和高锰酸钾反应得到。^[1]它和高氯酸四氨合铜(II)一样，受热快速分解。^[2]它在水中煮沸，发生以下反应：

[Cu(NH₃)₄](MnO₄)₂ + 2 H₂O → Cu(OH)₂ + 2 NH₃ + 2 NH₄MnO₄

氨从反应体系中离去使反应向右（高锰酸铵的方向）进行。^[3]对其缓慢加热，它在313~423 K脱氨，得到Cu(MnO₄)₂中间体，进一步加热，其分解的最终产物为CuMn₂O₄。^[3]

它可以将苯腙^[4]或醇^[5]氧化为相应的羰基化合物。

参考文献

^ ^1.0 ^1.1 ^1.2 N. Seferiadis, E. Dubler, H. R. Oswald. Structure of tetraamminecopper(II) dipermanganate. Acta Crystallographica Section C Crystal Structure Communications. 1986-08-01, 42 (8): 942–945 [2022-07-27]. ISSN 0108-2701. doi:10.1107/S0108270186093927. （原始内容存档于2022-07-27）.
^ Gorbunov, V. V.; Shmagin, L. F. Combustion of copper(II) tetrammine salts. Fizika Goreniya i Vzryva, 1972. 8 (4): 523-526. ISSN 0430-6228.
^ ^3.0 ^3.1 László Kótai, Kalyan K. Banerji, István Sajó, János Kristóf, B. Sreedhar, Sándor Holly, Gábor Keresztury, Antal Rockenbauer. An Unprecedented-Type Intramolecular Redox Reaction of Solid Tetraamminecopper(2+) Bis(permanganate) ([Cu(NH3)4](MnO4)2) – A Low-Temperature Synthesis of Copper Dimanganese Tetraoxide-Type (CuMn2O4) Nanocrystalline Catalyst Precursors. Helvetica Chimica Acta. 2002-08, 85 (8): 2316–2327 [2022-07-27]. doi:10.1002/1522-2675(200208)85:83.0.CO;2-A.
^ Raghvendra Shukla, László Kótai, Pradeep K. Sharma, Kalyan K. Banerji. Kinetics and mechanism of the oxidative regeneration of carbonyl compounds from phenylhydrazones by tetramminecopper(2+) bis (permanganate). Journal of Chemical Research. 2003-04-01, 2003 (4): 184–185 [2022-07-27]. doi:10.3184/030823403103173660 （英语）.
^ Hassani, H.; Zadah, E. Hoosein. Tetraammine copper(II) dipermanganate: a mild and efficient reagent for oxidation of alcohol to corresponding carbonyl compound. Organic Chemistry: An Indian Journal, 2015. 11 (11): 377-380. ISSN 0974-7516.

[actac-1] 1.0 ^1.1 ^1.2 N. Seferiadis, E. Dubler, H. R. Oswald. Structure of tetraamminecopper(II) dipermanganate. Acta Crystallographica Section C Crystal Structure Communications. 1986-08-01, 42 (8): 942–945 [2022-07-27]. ISSN 0108-2701. doi:10.1107/S0108270186093927. （原始内容存档于2022-07-27）.

[2] Gorbunov, V. V.; Shmagin, L. F. Combustion of copper(II) tetrammine salts. Fizika Goreniya i Vzryva, 1972. 8 (4): 523-526. ISSN 0430-6228.

[Helv-3] 3.0 ^3.1 László Kótai, Kalyan K. Banerji, István Sajó, János Kristóf, B. Sreedhar, Sándor Holly, Gábor Keresztury, Antal Rockenbauer. An Unprecedented-Type Intramolecular Redox Reaction of Solid Tetraamminecopper(2+) Bis(permanganate) ([Cu(NH3)4](MnO4)2) – A Low-Temperature Synthesis of Copper Dimanganese Tetraoxide-Type (CuMn2O4) Nanocrystalline Catalyst Precursors. Helvetica Chimica Acta. 2002-08, 85 (8): 2316–2327 [2022-07-27]. doi:10.1002/1522-2675(200208)85:83.0.CO;2-A.

[4] Raghvendra Shukla, László Kótai, Pradeep K. Sharma, Kalyan K. Banerji. Kinetics and mechanism of the oxidative regeneration of carbonyl compounds from phenylhydrazones by tetramminecopper(2+) bis (permanganate). Journal of Chemical Research. 2003-04-01, 2003 (4): 184–185 [2022-07-27]. doi:10.3184/030823403103173660 （英语）.

[5] Hassani, H.; Zadah, E. Hoosein. Tetraammine copper(II) dipermanganate: a mild and efficient reagent for oxidation of alcohol to corresponding carbonyl compound. Organic Chemistry: An Indian Journal, 2015. 11 (11): 377-380. ISSN 0974-7516.

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