1-三十二烷醇

化合物

1-三十二烷醇是一种有机化合物,化学式为C32H66O。它可由三十二酸甲酯和氢化铝锂四氢呋喃中反应制得。[3]三苯基膦存在下,它和N-溴代丁二酰亚胺二氯甲烷中反应,可以得到1-溴三十二烷。[4]它和乙酸酐反应,得到乙酸三十二烷基酯。[5]

1-三十二烷醇
IUPAC名
Dotriacontan-1-ol
别名 正三十二烷醇
识别
CAS号 6624-79-9  checkY
PubChem 96117
ChemSpider 86761
SMILES
 
  • OCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC
InChI
 
  • 1/C32H66O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19-20-21-22-23-24-25-26-27-28-29-30-31-32-33/h33H,2-32H2,1H3
InChIKey QOEHNLSDMADWEF-UHFFFAOYAH
性质
化学式 C32H66O
摩尔质量 466.87 g·mol−1
熔点 89 °C(362 K)[1]
81—82 °C(354—355 K)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Sosa, A. Chemical composition of a Mediterranean species of the Ericaceae family, Arbutus unedo. Bulletin de la Societe de Chimie Biologique, 1950. 32: 344-356.
  2. ^ Mathew, Joseph; George, V. Bioactive compounds from Acrotrema arnottianum. Asian Journal of Chemistry, 2006. 18 (4): 2747-2755.
  3. ^ Rao, S. Jagadishwar; Bhalerao, U. T.; Tilak, B. D. A new synthesis of long chain acid esters and carbinols. Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1987. 26B (3): 208-211.
  4. ^ Alexander Scholte, Sebastian Hauche, Matthias Wagner, Marko Prehm, Silvio Poppe, Changlong Chen, Feng Liu, Xiangbing Zeng, Goran Ungar, Carsten Tschierske. A self-assembled liquid crystal honeycomb of highly stretched (3-1-1)-hexagons. Chemical Communications. 2020, 56 (1): 62–65 [2021-11-27]. ISSN 1359-7345. doi:10.1039/C9CC08502E (英语). 
  5. ^ Euripides G. Stephanou. Analysis of anthropogenic and biogenic lipids in the aerosol of a coastal area in East Mediterranean Sea. Fresenius' Journal of Analytical Chemistry. 1991, 339 (10): 780–784 [2021-11-27]. ISSN 0937-0633. doi:10.1007/BF00321744 (英语).