打开主菜单

2,2'-二苯醚二甲酸是一种有机化合物,化学式为C14H10O5。它可由二苯醚二氧化碳丁基锂反应得到。[3]也可由邻溴甲苯邻甲基苯酚为原料反应得到。[4]含侧链邻位甲基二苯醚经氧化后生成该有机物。[5]它可以和等金属形成配位化合物[6]

2,2'-二苯醚二甲酸
英文名 2,​2'-​oxybisbenzoic acid
别名 2,2'-二羧基二苯醚
识别
CAS号 37424-29-6  ✓
性质
化学式 C14H10O5
摩尔质量 258.23 g·mol⁻¹
熔点 230 °C(503 K)[1]
溶解性 6.7 g[2]
pKa 2.96±0.36[2]
若非注明,所有数据均出自一般条件(25 ℃,100 kPa)下。

参考文献编辑

  1. ^ Richard H. F. Manske, Archie E. Ledingham. Synthesis and Reactions of Some Dibenzoxepins. Journal of the American Chemical Society. 1950-10, 72 (10): 4797–4799 [2018-09-22]. ISSN 0002-7863. doi:10.1021/ja01166a128 (英语). 
  2. ^ 2.0 2.1 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2018 ACD/Labs). Retrieved from SciFinder. [2018-9-22]
  3. ^ Heinz W. Gschwend, Herman R. Rodriguez. Heteroatom-Facilitated Lithiations. American Cancer Society. 2005: 1–360 [2018-12-04T15:48:36Z]. ISBN 9780471264187. doi:10.1002/0471264180.or026.01 (英语). 
  4. ^ Voegtle, Fritz; Kleiner, Thomas; Leppkes, Reinhard; Laeubli, Markus Werner; Ammann, Daniel; Simon, Wilhelm. Neutral ionophores with selectivity for sodium ion. Chemische Berichte, 1983. 116 (5): 2028-2034.
  5. ^ Hellwinkel, Dieter; Bohnet, Siegbert. Dibenzocyclooctene-​, dibenzochalcocine-​, and diarenochalconinediones. Chemische Berichte, 1987. 120 (7). 1151-1173.
  6. ^ Bi-Feng Huang, Tian Sun, Zahra Sharifzadeh, Meng-Yi Lv, Hong-Ping Xiao, Xin-Hua Li, Ali Morsali. Multinuclear coordination polymers constructed from V-shaped multicarboxylate and bis(imidazol-1-ylmethyl)-benzene ligand: Syntheses, crystal structures, and luminescent properties. Inorganica Chimica Acta. 2013-08, 405: 83–90 [2018-09-22]. ISSN 0020-1693. doi:10.1016/j.ica.2013.05.019.