3-(2-乙基己氧基)-1,2-丙二醇

化合物

3-(2-乙基己氧基)-1,2-丙二醇是一种有机化合物,化学式为C11H24O3。它可由丙三醇2-乙基己酸氢气催化下反应制得;[1]或由异辛基缩水甘油醚对甲苯磺酸催化下水解得到。[2]它和硫酸二甲酯磷酸三甲酯在一定条件下反应,可以得到3-[(2,3-二甲氧基丙氧基)甲基]庚烷。[1][3]

3-(2-乙基己氧基)-1,2-丙二醇
别名 乙基己基甘油
辛氧基甘油
甘油单异辛基醚
识别
CAS号 70445-33-9  checkY
PubChem 9859093
性质
化学式 C11H24O3
摩尔质量 204.31 g·mol⁻¹
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ 1.0 1.1 Marc Sutter, Wissam Dayoub, Estelle Métay, Yann Raoul, Marc Lemaire. 1,2,3-Trimethoxypropane and Glycerol Ethers as Bio-Sourced Solvents from Glycerol. Synthesis by Solvent-Free Phase-Transfer Catalysis and Utilization as an Alternative Solvent in Chemical Transformations. ChemCatChem. 2013-10, 5 (10): 2893–2904 [2021-11-18]. doi:10.1002/cctc.201300458 (英语). 
  2. ^ Shirasawa, Takeshi; Oka, Hiroshi; Morishita, Mitsugu; Okutsu, Munenao. Preparation of glyceryl ethers by hydrolysis of glycidyl ethers with decreased loss of water. 2003. JP 2003267901 A.
  3. ^ Marie‐Christine Duclos, Aurélien Herbinski, Anne‐Sophie Mora, Estelle Métay, Marc Lemaire. Methylation of Polyols with Trimethylphosphate in the Presence of a Lewis or Brønsted Acid Catalyst. ChemSusChem. 2018-02-09, 11 (3): 547–551 [2021-11-18]. ISSN 1864-5631. doi:10.1002/cssc.201701841 (英语).