5,15-二苯基-10,20-二(4-吡啶基)卟啉
5,15-二苯基-10,20-二(4-吡啶基)卟啉是一种有机化合物，化学式为C42H28N6。它可由吡咯、苯甲醛和4-吡啶甲醛按2:1:1化学计量比在丙酸中于150 °C回流反应，经柱分离后得到。[2]它和碘甲烷反应，得到相应的N-甲基吡啶鎓卟啉二碘化物。[3]它可以和金属形成配位化合物。[4][5]
| 5,15-二苯基-10,20-二(4-吡啶基)卟啉 | |
|---|---|
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| 识别 | |
| CAS号 | 71410-72-5 
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| 性质 | |
| 化学式 | C42H28N6 |
| 摩尔质量 | 616.71 g·mol−1 |
| 密度 | 1.293±0.06 g·cm−3（20 °C）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2021 ACD/Labs). Retrieved from SciFinder. [2021-07-03].
- ^ Zhou, Guojun; Wang, Bo; Cao, Rui. Acid Catalysis in Confined Channels of Metal–Organic Frameworks: Boosting Orthoformate Hydrolysis in Basic Solutions. Journal of the American Chemical Society. 2020, 142 (35): 14848–14853. ISSN 0002-7863. doi:10.1021/jacs.0c07257.
- ^ Amanda M. Slomp, Sandra M.W. Barreira, Luise Z.B. Carrenho, Camila C. Vandresen, Ingrid F. Zattoni, Stephanie M.S. Ló, Juliana C.C. Dallagnol, Diogo R.B. Ducatti, Alexandre Orsato, M. Eugênia R. Duarte, Miguel D. Noseda, Michel F. Otuki, Alan G. Gonçalves. Photodynamic effect of meso -(aryl)porphyrins and meso -(1-methyl-4-pyridinium)porphyrins on HaCaT keratinocytes. Bioorganic & Medicinal Chemistry Letters. 2017-01, 27 (2): 156–161 [2021-07-03]. doi:10.1016/j.bmcl.2016.11.094. （原始内容存档于2018-06-10） （英语）.
- ^ Kang, Byungman; Totten, Ryan K.; Weston, Mitchell H.; Hupp, Joseph T.; Nguyen, SonBinh T. Cyclic metalloporphyrin dimers and tetramers: tunable shape-selective hosts for fullerenes. Dalton Transactions. 2012, 41 (39): 12156. ISSN 1477-9226. doi:10.1039/c2dt31126g.
- ^ Mariangela Boccalon, Elisabetta Iengo, Paolo Tecilla. New meso-substituted trans-A2B2 di(4-pyridyl)porphyrins as building blocks for metal-mediated self-assembling of 4 + 4 Re(i)–porphyrin metallacycles. Organic & Biomolecular Chemistry. 2013, 11 (24): 4056 [2021-07-03]. ISSN 1477-0520. doi:10.1039/c3ob40452h （英语）.