PCN-14是一种金属有机框架材料,由铜(II)和5,5'-(9,10-蒽二基)二(1,3-苯二甲酸)配体(H4adip)连接而成,为二水合物。最初于2008年被制得。[1][2]

PCN-14
别名 Cu-PCN-14
识别
CAS号 1006599-75-2  checkY
性质
化学式 C270H162Cu18O90
摩尔质量 5989.9 g·mol⁻¹
外观 绿色晶体(二水二DMF合物)[1]
结构
晶体结构 菱方晶系,R3c(二水二DMF合物)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

制备

编辑

硝酸铜2.5水合物、H4adip配体加入至DMF溶剂中,并滴加氟硼酸,在75 °C进行溶剂热反应,可以制得PCN-14。[1]

性质

编辑

PCN-14可以高效地吸附甲烷[1]氢气[3]

参考文献

编辑
  1. ^ 1.0 1.1 1.2 1.3 Shengqian Ma, Daofeng Sun, Jason M. Simmons, Christopher D. Collier, Daqiang Yuan, Hong-Cai Zhou. Metal-Organic Framework from an Anthracene Derivative Containing Nanoscopic Cages Exhibiting High Methane Uptake. Journal of the American Chemical Society. 2008-1, 130 (3): 1012–1016 [2019-05-28]. ISSN 0002-7863. doi:10.1021/ja0771639. (原始内容存档于2020-08-01) (英语). 
  2. ^ 2.0 2.1 Shengqian Ma, Jason M. Simmons, Daofeng Sun, Daqiang Yuan, Hong-Cai Zhou. Porous Metal-Organic Frameworks Based on an Anthracene Derivative: Syntheses, Structure Analysis, and Hydrogen Sorption Studies. Inorganic Chemistry. 2009-06-15, 48 (12): 5263–5268 [2019-05-28]. ISSN 0020-1669. doi:10.1021/ic900217t (英语). 
  3. ^ Tony Pham, Katherine A. Forrest, Brian Space. An unusual H 2 sorption mechanism in PCN-14: insights from molecular simulation. Physical Chemistry Chemical Physics. 2016, 18 (31): 21421–21430 [2019-05-28]. ISSN 1463-9076. doi:10.1039/C6CP02650H (英语).