十四烷基三己基癸酸𬭸
十四烷基三己基癸酸𬭸是一种季𬭸盐，化学式为[(C6H13)3PC14H29]+CH3(CH2)8COO−。它可由十四烷基三己基氯化𬭸和癸酸在氢氧化钠的存在下于水中反应得到。[2]癸酸和相应的氢氧化𬭸在乙醇中反应，也能得到产物。[3]它可作为溶剂，溶解硫、硒、碲，其稀溶液（<1wt%）分别为蓝色、橙色和紫色；溶解硫的浓溶液为暗红色。[4]
| 十四烷基三己基癸酸𬭸 | |
|---|---|
phosphonium_decanoate.svg)
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| 别名 | 十四烷基三正己基癸酸𬭸 三己基十四烷基癸酸𬭸 Cyphos IL 103 |
| 识别 | |
| CAS号 | 465527-65-5 
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| 性质 | |
| 化学式 | C42H87O2P |
| 摩尔质量 | 655.11 g·mol⁻¹ |
| 密度 | 0.885 g·cm−3[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献 编辑
- ^ K.I. Park, M. Xanthos. A study on the degradation of polylactic acid in the presence of phosphonium ionic liquids. Polymer Degradation and Stability. 2009-05, 94 (5): 834–844 [2021-01-19]. doi:10.1016/j.polymdegradstab.2009.01.030. （原始内容存档于2018-07-01） （英语）.
- ^ Anna Cieniecka-Rosłonkiewicz, Juliusz Pernak, Joanna Kubis-Feder, Alwar Ramani, Allan J. Robertson, Kenneth R. Seddon. Synthesis, anti-microbial activities and anti-electrostatic properties of phosphonium-based ionic liquids. Green Chemistry. 2005, 7 (12): 855 [2021-01-19]. ISSN 1463-9262. doi:10.1039/b508499g （英语）.
- ^ Qiwei Yang, Dan Xu, Jingzhu Zhang, Yaoming Zhu, Zhiguo Zhang, Chao Qian, Qilong Ren, Huabin Xing. Long-Chain Fatty Acid-Based Phosphonium Ionic Liquids with Strong Hydrogen-Bond Basicity and Good Lipophilicity: Synthesis, Characterization, and Application in Extraction. ACS Sustainable Chemistry & Engineering. 2015-02-02, 3 (2): 309–316 [2021-01-19]. ISSN 2168-0485. doi:10.1021/sc5006796. （原始内容存档于2022-03-20） （英语）.
- ^ Boros, Èva; Earle, Martyn J.; Gîlea, Manuela A.; Metlen, Andreas; Mudring, Anja-Verena; Rieger, Franziska; Robertson, Allan J.; Seddon, Kenneth R.; Tomaszowska, Alina A.; Trusov, Lev; Vyle, Joseph S. On the dissolution of non-metallic solid elements (sulfur, selenium, tellurium and phosphorus) in ionic liquids. Chem. Commun. 2010, 46 (5): 716–718. ISSN 1359-7345. doi:10.1039/B910469K.