硫代乙酸-S-乙酯

化合物

硫代乙酸-S-乙酯是一种有机化合物,化学式为CH3C(O)SC2H5。它可由乙酰氯乙硫醇氯氧化铋催化下反应制得。[2]它和碘苯粉在镍盐、联吡啶催化下反应,可以得到苯甲酸-S-乙酯和苯乙硫醚[3]

硫代乙酸-S-乙酯
识别
CAS号 625-60-5  checkY
PubChem 61171
ChemSpider 55117
性质
化学式 C4H8OS
摩尔质量 104.17 g·mol−1
沸点 114 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Hawkins, Peter J.; Tarbell, D. Stanley. Studies on Model Compounds for Coenzyme A. A Kinetic Study of Aminolysis and Hydrolysis of Ethyl Thioacetate and β-Acetaminoethyl Thioacetate in Aqueous Solution. Journal of the American Chemical Society. 1953, 75 (12): 2982–2985. ISSN 0002-7863. doi:10.1021/ja01108a057. 
  2. ^ Ghosh, Rina; Maiti, Swarupananda; Chakraborty, Arijit. Facile catalyzed acylation of heteroatoms using BiCl3 generated in situ from the procatalyst BiOCl and acetyl chloride. Tetrahedron Letters. 2004, 45 (36): 6775–6778. doi:10.1016/j.tetlet.2004.07.044. 
  3. ^ Mai, Wen-Peng; Sui, Hong-Da; Lv, Ming-Xiu; Lu, Kui. Nickel-catalyzed carbonylation of thioacetates with aryl iodides via CO insertion and C–S bond cleavage. Journal of Chemical Research. 2021, 45 (9-10): 890–895. ISSN 1747-5198. doi:10.1177/17475198211028114.