2-氯-2-硝基丙烷
化合物
2-氯-2-硝基丙烷是一种有机化合物,化学式为C3H6ClNO2。它可由2-氯-2-亚硝基丙烷和臭氧在二氯甲烷中反应得到,[3]或通过2-硝基丙烷在氢氧化钾存在下和N-氯代丁二酰亚胺反应制得。[4]它和炔基锂反应,可以得到2-硝基丙-2-基炔烃。[5]它和苯甲硫醇钠反应,可以得到二苄基二硫和2,3-二甲基-2,3-二硝基丁烷。[6]
2-氯-2-硝基丙烷 | |
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识别 | |
CAS号 | 594-71-8 ![]() |
性质 | |
化学式 | C3H6ClNO2 |
摩尔质量 | 123.54 g·mol−1 |
密度 | 1.230 g·cm−3(19 °C)[1] |
沸点 | 130-132 °C[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
编辑- ^ "Hazardous Substances Data Bank" data were obtained from the National Library of Medicine (US). Retrieved from SciFinder. [2022-08-18].
- ^ Warriner (编). Category 4, Compounds with Two Carbon Heteroatom Bonds: Acetals: Hal/X and O/O, S, Se, Te 1. Stuttgart: Georg Thieme Verlag. 2007 [2022-08-18]. ISBN 9783131188113. doi:10.1055/sos-sd-029-00297. (原始内容存档于2022-05-30) (英语).
- ^ Bobinski, Thomas. 2-Chloro-2-nitrosopropane. e-EROS Encyclopedia of Reagents for Organic Synthesis. 2015. 1-4.
- ^ A. Amrollah-Madjdabadi, R. Beugelmans, A. Lechevallier. A Convenient Method For The Preparation of gem -Halonitro Compounds. Synthesis. 1986, 1986 (10): 828–830 [2022-08-18]. ISSN 0039-7881. doi:10.1055/s-1986-31792. (原始内容存档于2018-06-04) (英语).
- ^ Mikolaj Jawdosiuk, Mieczyslaw Makosza, B. Mudryk, Glen A. Russell. Formation of α-nitro-acetylenes by the coupling reactions of lithium acetylides with 2-chloro-2-nitropropane or 2,2-dinitropropane. J. Chem. Soc., Chem. Commun. 1979, (11): 488–489 [2022-08-18]. ISSN 0022-4936. doi:10.1039/C39790000488 (英语).
- ^ Suleiman I. Al-Khalil, W. Russell Bowman, Katherine Gaitonde, Madeleine A. Marley (née Nagel), Geoffrey D. Richardson. Radical-nucleophilic substitution (SRN1) reactions. Part 7. Reactions of aliphatic α-substituted nitro compounds.. Journal of the Chemical Society, Perkin Transactions 2. 2001, (9): 1557–1565 [2022-08-18]. doi:10.1039/b103350f.