9,10-二氢菲

9,10-二氢菲
识别
CAS号	776-35-2
SMILES	C=1C=CC2=C(C1)C=3C=CC=CC3CC2;
性质
化学式	C14H12
摩尔质量	180.25 g·mol−1
熔点	35—35.5 °C（308.1—308.6 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

9,10-二氢菲是一种有机化合物，化学式为C₁₄H₁₂。它可由菲在催化下加氢制得^[2]。它可以被混酸^[3]或硝酸铋^[4]硝化，得到2,7-二硝基-9,10-二氢菲；它在三氯化铁催化下和溴反应，可以得到2,7-二溴-9,10-二氢菲^[5]。

参考文献

^ Hall, D. Muriel; Lesslie, Mary S.; Turner, E. E. 143. 9 : 10-Dihydrophenanthrenes. Part I. The formation of 9 : 10-dihydrophenanthrene from 2 : 2′-disubstituted diphenyls. J. Chem. Soc. (Royal Society of Chemistry (RSC)). 1950, 0 (0): 711–713. ISSN 0368-1769. doi:10.1039/jr9500000711.
^ Amer, Ibrahim; Amer, Hamdullah; Ascher, Rachel; Blum, Jochanan; Sasson, Yoel; Vollhardt, K.Peter C. Hydrogenation of arenes by the RhCl3-aliquat® 336 catalyst. Journal of Molecular Catalysis. 1987-02, 39 (2): 185–194. doi:10.1016/0304-5102(87)80062-7.
^ Nelsen, Stephen F.; Luo, Yun; Weaver, Michael N.; Lockard, Jenny V.; Zink, Jeffrey I. Optical Spectra of Protected Diamine 10-Bond-Bridged Intervalence Radical Cations Related to N,N,N‘N‘-Tetraalkylbenzidine. The Journal of Organic Chemistry (American Chemical Society (ACS)). 2006-05-01, 71 (11): 4286–4295. ISSN 0022-3263. doi:10.1021/jo060466l.
^ Yadav, Ram N.; Salazar, Leonardo; Singh, Amrendra Kumar; Banik, Bimal Krishna. Microwave-induced bismuth nitrate-impregnated clay-mediated novel dinitration of 9,10- dihydrophenanthrene: a precursor for new heterocycles. Heterocyclic Letters, 2018. 8 (2): 273-276.
^ Sasaki, Shunsuke; Niko, Yosuke; Klymchenko, Andrey S.; Konishi, Gen-ichi. Design of donor–acceptor geometry for tuning excited-state polarization: fluorescence solvatochromism of push–pull biphenyls with various torsional restrictions on their aryl–aryl bonds. Tetrahedron (Elsevier BV). 2014, 70 (41): 7551–7559. ISSN 0040-4020. doi:10.1016/j.tet.2014.08.002.

[1] Hall, D. Muriel; Lesslie, Mary S.; Turner, E. E. 143. 9 : 10-Dihydrophenanthrenes. Part I. The formation of 9 : 10-dihydrophenanthrene from 2 : 2′-disubstituted diphenyls. J. Chem. Soc. (Royal Society of Chemistry (RSC)). 1950, 0 (0): 711–713. ISSN 0368-1769. doi:10.1039/jr9500000711.

[2] Amer, Ibrahim; Amer, Hamdullah; Ascher, Rachel; Blum, Jochanan; Sasson, Yoel; Vollhardt, K.Peter C. Hydrogenation of arenes by the RhCl3-aliquat® 336 catalyst. Journal of Molecular Catalysis. 1987-02, 39 (2): 185–194. doi:10.1016/0304-5102(87)80062-7.

[3] Nelsen, Stephen F.; Luo, Yun; Weaver, Michael N.; Lockard, Jenny V.; Zink, Jeffrey I. Optical Spectra of Protected Diamine 10-Bond-Bridged Intervalence Radical Cations Related to N,N,N‘N‘-Tetraalkylbenzidine. The Journal of Organic Chemistry (American Chemical Society (ACS)). 2006-05-01, 71 (11): 4286–4295. ISSN 0022-3263. doi:10.1021/jo060466l.

[4] Yadav, Ram N.; Salazar, Leonardo; Singh, Amrendra Kumar; Banik, Bimal Krishna. Microwave-induced bismuth nitrate-impregnated clay-mediated novel dinitration of 9,10- dihydrophenanthrene: a precursor for new heterocycles. Heterocyclic Letters, 2018. 8 (2): 273-276.

[5] Sasaki, Shunsuke; Niko, Yosuke; Klymchenko, Andrey S.; Konishi, Gen-ichi. Design of donor–acceptor geometry for tuning excited-state polarization: fluorescence solvatochromism of push–pull biphenyls with various torsional restrictions on their aryl–aryl bonds. Tetrahedron (Elsevier BV). 2014, 70 (41): 7551–7559. ISSN 0040-4020. doi:10.1016/j.tet.2014.08.002.

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[5]

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9,10-二氢菲

识别
CAS号	776-35-2 ^Y
SMILES	C=1C=CC2=C(C1)C=3C=CC=CC3CC2
性质
化学式	C₁₄H₁₂
摩尔质量	180.25 g·mol⁻¹
熔点	35—35.5 °C（308.1—308.6 K）^[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。