9,10-二氢菲

化合物

9,10-二氢菲是一种有机化合物,化学式为C14H12。它可由在催化下加氢制得[2]。它可以被混酸[3]硝酸铋[4]硝化,得到2,7-二硝基-9,10-二氢菲;它在三氯化铁催化下和反应,可以得到2,7-二溴-9,10-二氢菲[5]

9,10-二氢菲
识别
CAS号 776-35-2  checkY
SMILES
 
  • C=1C=CC2=C(C1)C=3C=CC=CC3CC2
性质
化学式 C14H12
摩尔质量 180.25 g·mol−1
熔点 35—35.5 °C(308.1—308.6 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ Hall, D. Muriel; Lesslie, Mary S.; Turner, E. E. 143. 9 : 10-Dihydrophenanthrenes. Part I. The formation of 9 : 10-dihydrophenanthrene from 2 : 2′-disubstituted diphenyls. J. Chem. Soc. (Royal Society of Chemistry (RSC)). 1950, 0 (0): 711–713. ISSN 0368-1769. doi:10.1039/jr9500000711. 
  2. ^ Amer, Ibrahim; Amer, Hamdullah; Ascher, Rachel; Blum, Jochanan; Sasson, Yoel; Vollhardt, K.Peter C. Hydrogenation of arenes by the RhCl3-aliquat® 336 catalyst. Journal of Molecular Catalysis. 1987-02, 39 (2): 185–194. doi:10.1016/0304-5102(87)80062-7. 
  3. ^ Nelsen, Stephen F.; Luo, Yun; Weaver, Michael N.; Lockard, Jenny V.; Zink, Jeffrey I. Optical Spectra of Protected Diamine 10-Bond-Bridged Intervalence Radical Cations Related to N,N,NN‘-Tetraalkylbenzidine. The Journal of Organic Chemistry (American Chemical Society (ACS)). 2006-05-01, 71 (11): 4286–4295. ISSN 0022-3263. doi:10.1021/jo060466l. 
  4. ^ Yadav, Ram N.; Salazar, Leonardo; Singh, Amrendra Kumar; Banik, Bimal Krishna. Microwave-induced bismuth nitrate-impregnated clay-mediated novel dinitration of 9,10- dihydrophenanthrene: a precursor for new heterocycles. Heterocyclic Letters, 2018. 8 (2): 273-276.
  5. ^ Sasaki, Shunsuke; Niko, Yosuke; Klymchenko, Andrey S.; Konishi, Gen-ichi. Design of donor–acceptor geometry for tuning excited-state polarization: fluorescence solvatochromism of push–pull biphenyls with various torsional restrictions on their aryl–aryl bonds. Tetrahedron (Elsevier BV). 2014, 70 (41): 7551–7559. ISSN 0040-4020. doi:10.1016/j.tet.2014.08.002.