5-乙烯基-2H-四唑
5-乙烯基-2H-四唑是一种有机化合物，化学式为C3H4N4。它可由丙烯腈和叠氮化钠在催化下反应制得。[1][2]在过硫酸钾存在下，使用钴或镍电极电解，可以得到暗粉色的聚(双乙烯基四唑合钴水合物)或淡紫色的聚(双乙烯基四唑合镍水合物)。[3]它和溴在三氯甲烷中反应，可以得到5-(1,2-二溴乙基)-2H-四唑。[4]
| 5-乙烯基-2H-四唑 | |
|---|---|
| |
| 识别 | |
| CAS号 | 18755-47-0 
|
| 性质 | |
| 化学式 | C3H4N4 |
| 摩尔质量 | 96.09 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
编辑- ^ Parviz Movaheditabar, Mohammad Javaherian, Valiollah Nobakht. CuO/aluminosilicate as an efficient heterogeneous nanocatalyst for the synthesis and sequential one-pot functionalization of 5-substituted-1H-tetrazoles. Reaction Kinetics, Mechanisms and Catalysis. 2017-10, 122 (1): 217–228 [2022-11-06]. ISSN 1878-5190. doi:10.1007/s11144-017-1211-1 （英语）.
- ^ Charles W. Rees, Sivaprasad Sivadasan, Andrew J. P. White, David J. Williams. Conversion of tetrazoles into hydrazonoyl chlorides. Novel donor–dithiazolium interactions. Journal of the Chemical Society, Perkin Transactions 1. 2002-06-27, (13): 1535–1542 [2022-11-06]. doi:10.1039/b202211g.
- ^ K. S. Margaryan, S. A. Sargisyan. Metal-containing polymers based on 5-vinyltetrazole. Russian Journal of General Chemistry. 2015-11, 85 (11): 2614–2616 [2022-11-06]. ISSN 1070-3632. doi:10.1134/S1070363215110183 （英语）.
- ^ George K. Belousov, Alexander V. Zuraev. New approach to the synthesis of tetrazole-containing buta-1,3-diynes: The total synthesis of 1,4-bis(2-(tert-butyl)-2H-tetrazol-5-yl)buta-1,3-diyne. Tetrahedron Letters. 2019-11, 60 (45): 151217 [2022-11-06]. doi:10.1016/j.tetlet.2019.151217 （英语）.