4-硝基苯甲醛

4-硝基苯甲醛
	IUPAC名; 4-Nitrobenzaldehyde
別名	p-Nitrobenzaldehyde
性質
化學式	C7H5NO3
摩爾質量	151.12 g·mol−1
外觀	略帶黃色的晶體粉末
密度	1.546 g/cm3
熔點	103—106 °C（376—379 K）
沸點	300 °C（573 K）
磁化率	−66.57·10−6 cm3/mol
識別
CAS號	555-16-8
PubChem	541
ChemSpider	526
SMILES	O=[N+]([O-])c1ccc(C=O)cc1;
InChI	1/C7H5NO3/c9-5-6-1-3-7(4-2-6)8(10)11/h1-5H;
InChIKey	BXRFQSNOROATLV-UHFFFAOYAO
ChEBI	66926
危險性
	GHS危險性符號;
H-術語	H317, H319
P-術語	P280, P305+351+338
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

4-硝基苯甲醛是一種有機化合物，化學式為C₇H₅NO₃，可以以4-硝基甲苯為原料製得。^[3]

它可以被水合肼在乙醇中還原為4-氨基苯甲醛，^[4]或被硼氫化鈉還原為4-硝基苯甲醇，^[5]硼氫化鈉也可將其還原為4-氨基苯甲醇^[6]。它可以被過氧化氫氧化為4-硝基苯甲酸。^[7]

參考文獻編輯

^ ^1.0 ^1.1 4-Nitrobenzaldehyde(555-16-8) (Date Accessed 17 April 2013)
^ ^2.0 ^2.1 來源：Sigma-Aldrich Co., 4-Nitrobenzaldehyde （4 May 2011查閱）.
^ 4-Nitrobenzaldehyd （頁面存檔備份，存於網際網路檔案館）, Versuchsvorschrift aus: Organic Syntheses, Coll. Vol. 2, p. 441 (1943); Vol. 18, p. 61 (1938).
^ Shuo Chen, Li-Li Ling, Shun-Feng Jiang, Hong Jiang. Selective hydrogenation of nitroarenes under mild conditions by the optimization of active sites in a well defined Co@NC catalyst. Green Chemistry. 2020, 22 (17): 5730–5741 [2021-05-18]. ISSN 1463-9262. doi:10.1039/D0GC01835J （英語）.
^ Naimi-Jamal, M. R.; Mokhtari, J.; Dekamin, Mohammad G. Fast and efficient method for quantitative reduction of carbonyl compounds by NaBH4 under solvent-free conditions. Proceedings of the International Electronic Conference on Synthetic Organic Chemistry, 11th, Nov. 1-30, 2007: a017/1-a017/5. ISBN 3-906980-19-7.
^ Wei-Guo Jia, Mei Li, Xue-Ting Zhi, Li-Li Gao, Jun Du. Copper(II) complex with oxazoline ligand: Synthesis, structures and catalytic activity for nitro compounds reduction. Journal of Molecular Structure. 2020-10, 1217: 128349 [2021-05-18]. doi:10.1016/j.molstruc.2020.128349. （原始內容存檔於2020-05-09）（英語）.
^ Sagar Sharma, Nilotpal Barooah, Jubaraj B. Baruah. Tris(3,5-dimethylpyrazole)copper(II) nitrate: as an oxidation catalyst. Journal of Molecular Catalysis A: Chemical. 2005-03, 229 (1-2): 171–176 [2021-05-18]. doi:10.1016/j.molcata.2004.11.019. （原始內容存檔於2018-06-05）（英語）.

[ChemicalBook-1] 1.0 ^1.1 4-Nitrobenzaldehyde(555-16-8) (Date Accessed 17 April 2013)

[SigmaAldrich-2] 2.0 ^2.1 來源：Sigma-Aldrich Co., 4-Nitrobenzaldehyde （4 May 2011查閱）.

[3] 4-Nitrobenzaldehyd （頁面存檔備份，存於網際網路檔案館）, Versuchsvorschrift aus: Organic Syntheses, Coll. Vol. 2, p. 441 (1943); Vol. 18, p. 61 (1938).

[4] Shuo Chen, Li-Li Ling, Shun-Feng Jiang, Hong Jiang. Selective hydrogenation of nitroarenes under mild conditions by the optimization of active sites in a well defined Co@NC catalyst. Green Chemistry. 2020, 22 (17): 5730–5741 [2021-05-18]. ISSN 1463-9262. doi:10.1039/D0GC01835J （英語）.

[5] Naimi-Jamal, M. R.; Mokhtari, J.; Dekamin, Mohammad G. Fast and efficient method for quantitative reduction of carbonyl compounds by NaBH4 under solvent-free conditions. Proceedings of the International Electronic Conference on Synthetic Organic Chemistry, 11th, Nov. 1-30, 2007: a017/1-a017/5. ISBN 3-906980-19-7.

[6] Wei-Guo Jia, Mei Li, Xue-Ting Zhi, Li-Li Gao, Jun Du. Copper(II) complex with oxazoline ligand: Synthesis, structures and catalytic activity for nitro compounds reduction. Journal of Molecular Structure. 2020-10, 1217: 128349 [2021-05-18]. doi:10.1016/j.molstruc.2020.128349. （原始內容存檔於2020-05-09）（英語）.

[7] Sagar Sharma, Nilotpal Barooah, Jubaraj B. Baruah. Tris(3,5-dimethylpyrazole)copper(II) nitrate: as an oxidation catalyst. Journal of Molecular Catalysis A: Chemical. 2005-03, 229 (1-2): 171–176 [2021-05-18]. doi:10.1016/j.molcata.2004.11.019. （原始內容存檔於2018-06-05）（英語）.

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4-硝基苯甲醛

參考文獻 編輯

參考文獻編輯