α,α,α-三硝基甲苯

α,α,α-三硝基甲苯是一種有機化合物,化學式為C7H5N3O6,是三硝基甲苯同分異構體之一。它可由α,α-二硝基苄基鉀和四氧化二氮三氯甲烷中反應得到。[2]它可以用於製備α-C-硝基[3]

α,α,α-三硝基甲苯
英文名 (Trinitromethyl)benzene
α,α,α-Trinitrotoluene
別名 (三硝基甲基)苯
識別
CAS號 67483-29-8  checkY
SMILES
 
  • c1ccccc1C([N+](=O)[O-])([N+](=O)[O-])[N+](=O)[O-]
性質
化學式 C7H5N3O6
摩爾質量 227.13 g·mol−1
熔點 4.5 °C(277.6 K)[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

編輯
  1. ^ Titov, A. I.; Smirnov, V. V. Effect of complex formation, ionization, and isomerization of organic compounds on their chemical activity in nitration. Synthesis of phenyltrinitromethane and its properties. Doklady Akademii Nauk SSSR, 1952. 83. 243-246. ISSN: 0002-3264.
  2. ^ Makhova, N. N.; Ovchinnikov, I. V.; Dubonos, V. G.; Strelenko, Yu. A.; Khmel?nitski, L. I. New methods for preparation of nitrile oxides and the corresponding disubstituted furoxans by reaction of N2O4 with salts of substituted dinitromethanes. Izvestiya Akademii Nauk, Seriya Khimicheskaya, 1993. 1: 147-151.
  3. ^ Shvarts, I. Sh.; Krayushkin, M. M.; Sevost'yanova, V. V.; Yarovenko, V. N. Synthesis and properties of α-C-nitrohydrazones. 2. Reaction of hydrazines with trinitromethyl components(俄文). Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya. 1979. 5. 1069-1073.