δ-癸內酯
化合物
δ-癸內酯，簡稱DDL，是一種內酯，化學式 C10H18O2。它天然微量存在於水果[1]和奶製品中。[2]它可以從化學和生物來源獲得。[3][4]從化學方法獲得的方法是2-戊基環戊酮的拜耳－維立格氧化反應；[5]而生物質方法是通過6-戊基-α-吡喃酮的氫化產生。[4] DDL應用於食品、[6]聚合物[7]和農業[8]。
| δ-癸內酯 | |
|---|---|
| |
| IUPAC名 6-Pentyloxan-2-one | |
| 識別 | |
| CAS號 | 705-86-2 
|
| PubChem | 12810 |
| ChemSpider | 12282 |
| SMILES |
|
| ChEBI | 87327 |
| 性質 | |
| 化學式 | C10H18O2 |
| 摩爾質量 | 170.25 g·mol−1 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參見 編輯
參考資料 編輯
- ^ Tamura, Hirotoshi; Appel, Markus; Richling, Elke; Schreier, Peter. Authenticity Assessment of γ- and δ-Decalactone from Prunus Fruits by Gas Chromatography Combustion/Pyrolysis Isotope Ratio Mass Spectrometry (GC-C/P-IRMS). Journal of Agricultural and Food Chemistry. 2005, 53 (13): 5397–5401. PMID 15969525. doi:10.1021/jf0503964.
- ^ Karagül-Yüceer, Yonca; Drake, Maryanne; Cadwallader, Keith R. Aroma-Active Components of Nonfat Dry Milk. Journal of Agricultural and Food Chemistry. 2001, 49 (6): 2948–2953. PMID 11409991. doi:10.1021/jf0009854.
- ^ Corma, Avelino; Iborra, Sara; Mifsud, María; Renz, Michael; Susarte, Manuel. A New Environmentally Benign Catalytic Process for the Asymmetric Synthesis of Lactones: Synthesis of the Flavouringδ-Decalactone Molecule. Advanced Synthesis & Catalysis. 2004, 346 (23): 257–262. doi:10.1002/adsc.200303234.
- ^ 4.0 4.1 Alam, Md. Imteyaz; Khan, Tuhin S.; Haider, M. Ali. Alternate Biobased Route to Produce δ-Decalactone: Elucidating the Role of Solvent and Hydrogen Evolution in Catalytic Transfer Hydrogenation. ACS Sustainable Chemistry & Engineering. 2019, 7 (3): 2894–2898. doi:10.1021/acssuschemeng.8b05014.
- ^ Corma, Avelino; Iborra, Sara; Mifsud, María; Renz, Michael; Susarte, Manuel. A New Environmentally Benign Catalytic Process for the Asymmetric Synthesis of Lactones: Synthesis of the Flavouring δ-Decalactone Molecule. Advanced Synthesis & Catalysis. 2004, 346 (23): 257–262. doi:10.1002/adsc.200303234.
- ^ The forty-ninth meeting of the Joint FAO/WHO Expert Committee on Food Additives; WHO food additive series 40; WHO: Geneva, 1998
- ^ Martello, Mark T.; Burns, Adam; Hillmyer, Marc. Bulk Ring-Opening Transesterification Polymerization of the Renewable δ-Decalactone Using an Organocatalyst. ACS Macro Letters. 2012, 1: 131–135. doi:10.1021/mz200006s.
- ^ Menger, D. J.; Van Loon, J. J. A.; Takken, W. Assessing the efficacy of candidate mosquito repellents against the background of an attractive source that mimics a human host. Medical and Veterinary Entomology. 2014, 28 (4): 407–413. PMID 24797537. S2CID 13106405. doi:10.1111/mve.12061.
- ^ Li, Guang; Roze, Uldis; Locke, David C. Warning Odor of the North American Porcupine(Erethizon dorsatum). Journal of Chemical Ecology. December 1997, 23 (12): 2737–2754. Bibcode:1997JSP....23.2737L. S2CID 36405223. doi:10.1023/A:1022511026529.