高氯酸釓

高氯酸釓
識別
CAS號	14017-52-8（無水） ; 15201-56-6（八水）
性質
化學式	Cl3GdO12
摩爾質量	455.6 g·mol−1
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

高氯酸釓是一種無機化合物，化學式為Gd(ClO₄)₃。它可由氧化釓和高氯酸（70~72%）在80 °C反應得到。^[1]它可以和二噁烷形成無色的Gd(ClO₄)₃·9H₂O·4C₄H₈O₂配合物晶體。^[2]它和myo-肌醇、乙酸鈉、氫氧化鈉反應，可以得到含巨型分子簇{Gd₁₄₀}的配合物。^[1]它和氯化鉻、2,2'-聯吡啶在pH=5.1下反應，可以得到[GdCr(bipy)₂(OH)₂(H₂O)₆](ClO₄)₄·2H₂O。^[3]

參考文獻

^ ^1.0 ^1.1 Xiu-Ying Zheng, You-Hong Jiang, Gui-Lin Zhuang, Da-Peng Liu, Hong-Gang Liao, Xiang-Jian Kong, La-Sheng Long, Lan-Sun Zheng. A Gigantic Molecular Wheel of {Gd 140 }: A New Member of the Molecular Wheel Family. Journal of the American Chemical Society. 2017-12-20, 139 (50): 18178–18181 [2023-03-15]. ISSN 0002-7863. doi:10.1021/jacs.7b11112. （原始內容存檔於2023-03-15）（英語）.
^ Vicentini, Geraldo; Perrier, Madeleine; Giesbrecht, Ernesto. The reaction of dioxane with the perchlorate hydrates of a few transition metals. Chemische Berichte, 1961. 94: 1153-1155.
^ Zhong‐Yi Li, Xiao‐Qun Wang, Jian‐Jun Zhang, Shu‐Qin Liu, Jun Ni, Ying‐Ji Sun. Synthesis, Structures, and Magnetic Properties of Binuclear [CrLn] (Ln = Gd or Dy) and Trinuclear [Cr 2 Ln] (Ln = Gd, Dy, or Tb) Heterometallic Clusters with 2,2′‐Bipyridine as Ligand. European Journal of Inorganic Chemistry. 2015-12, 2015 (34): 5702–5707 [2023-03-15]. ISSN 1434-1948. doi:10.1002/ejic.201500786 （英語）.

[jacs-1] 1.0 ^1.1 Xiu-Ying Zheng, You-Hong Jiang, Gui-Lin Zhuang, Da-Peng Liu, Hong-Gang Liao, Xiang-Jian Kong, La-Sheng Long, Lan-Sun Zheng. A Gigantic Molecular Wheel of {Gd 140 }: A New Member of the Molecular Wheel Family. Journal of the American Chemical Society. 2017-12-20, 139 (50): 18178–18181 [2023-03-15]. ISSN 0002-7863. doi:10.1021/jacs.7b11112. （原始內容存檔於2023-03-15）（英語）.

[2] Vicentini, Geraldo; Perrier, Madeleine; Giesbrecht, Ernesto. The reaction of dioxane with the perchlorate hydrates of a few transition metals. Chemische Berichte, 1961. 94: 1153-1155.

[3] Zhong‐Yi Li, Xiao‐Qun Wang, Jian‐Jun Zhang, Shu‐Qin Liu, Jun Ni, Ying‐Ji Sun. Synthesis, Structures, and Magnetic Properties of Binuclear [CrLn] (Ln = Gd or Dy) and Trinuclear [Cr 2 Ln] (Ln = Gd, Dy, or Tb) Heterometallic Clusters with 2,2′‐Bipyridine as Ligand. European Journal of Inorganic Chemistry. 2015-12, 2015 (34): 5702–5707 [2023-03-15]. ISSN 1434-1948. doi:10.1002/ejic.201500786 （英語）.

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