一碘化镓是一种无机化合物,化学式为GaI,或写作Ga4I4。它是低价的镓化合物,是很多镓化合物的活泼中间体。卤化镓(I)英语Gallium halides首次由Schnöckel等人得到晶体结构。[1]

一碘化镓
英文名 Gallium monoiodide
识别
CAS号 15605-68-2
PubChem 10963591
ChemSpider 9138803
SMILES
 
  • [Ga]I
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

它可由下法合成,并存在多种结构:[2]

GaI preparation details as provided by Malbrecht and coworkers.

GaI可以形成一些簇合物。[3]

参考文献

编辑
  1. ^ Dohmeier, Carsten; Loos, Dagmar; Schnöckel, Hansgeorg. Aluminum(I) and Gallium(I) Compounds: Syntheses, Structures, and Reactions. Angewandte Chemie International Edition in English. 1996, 35 (2): 129–149 [2021-10-29]. ISSN 1521-3773. doi:10.1002/anie.199601291. (原始内容存档于2021-11-02) (英语). 
  2. ^ Malbrecht, Brian J.; Dube, Jonathan W.; Willans, Mathew J.; Ragogna, Paul J. Addressing the Chemical Sorcery of "GaI": Benefits of Solid-State Analysis Aiding in the Synthesis of P→Ga Coordination Compounds. Inorganic Chemistry. 2014-09-15, 53 (18): 9644–9656. ISSN 0020-1669. PMID 25184621. doi:10.1021/ic501139w. 
  3. ^ Köstler, Wolfgang; Linti, Gerald (1997). "Synthesis and Structure of a Tetragallane [R4Ga4I3]− and a Polyhedral Nonagallane [R6Ga9]". Angewandte Chemie International Edition in English. 36 (23): 2644–2646. doi:10.1002/anie.199726441. ISSN 1521-3773.