四氯环氧乙烷

化合物

四氯环氧乙烷是一种有机化合物,化学式为C2Cl4O,它是四氯乙烯的可能的代谢产物。[3]它是稳定的化合物,但是加热可以重排为三氯乙酰氯[4]

四氯环氧乙烷
IUPAC名
tetrachlorooxirane
别名 Perchloroethylene oxide (PCEO), Epoxyperchlorovinyl, Tetrachloroepoxyethane
识别
CAS号 16650-10-5  checkY
PubChem 27973
ChemSpider 26022
SMILES
 
  • ClC1(Cl)C(Cl)(Cl)O1
性质
化学式 C2Cl4O
摩尔质量 181.83 g·mol−1
外观 liquid
密度 1.72 g/cm3[1]
熔点 –58 °C[2]
沸点 110 °C [1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

它可以代谢为三氯乙酰氯,并水解为三氯乙酸[5]

参考文献

编辑
  1. ^ 1.0 1.1 Yaws, C. L. (2015). The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals: Physical Properties for More Than 54,000 Organic and Inorganic Chemical Compounds, Coverage for C1 to C100 Organics and Ac to Zr Inorganics.
  2. ^ Notes - Preparation and Properties of Tetrachloroethylene Oxide Donald Frankel, Claude Johnson, and Harold Pitt The Journal of Organic Chemistry 1957 22 (9), 1119-1120 DOI: 10.1021/jo01360a614
  3. ^ Raat, W. K. d. (2003). 133 Tetrachloroethylene (PER). Sweden: Arbetslivsinstitutet.
  4. ^ R. W. Campbell & O. Vogl (1977) A Practical Synthesis of Tetrachloroethylene Oxide, Journal of Macromolecular Science: Part A - Chemistry, 11:3, 515-534, DOI: 10.1080/00222337708061286
  5. ^ Testa, B., Mayer, J. M. (2003). Hydrolysis in Drug and Prodrug Metabolism. page 633