2-硝基乙醇

化合物

2-硝基乙醇是一种有机化合物,化学式为NO2CH2CH2OH。它可由硝基甲烷甲醛在碱性条件下反应制得。[3]其它制备方法还有2-碘乙醇亚硝酸银的反应[4]环氧乙烷亚硝酸钠的反应[5]。它和乙酰氯反应,可以得到乙酸-2-硝基乙酯。[6]

2-硝基乙醇
别名 β-硝基乙醇
识别
CAS号 625-48-9  checkY
性质
化学式 C2H5NO3
摩尔质量 91.07 g·mol−1
密度 1.296 g·cm−3[1]
熔点 −80 °C[2]
沸点 102 °C(11 Torr)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ 1.0 1.1 Norman Levy, Charles W. Scaife, Arthur E. Wilder Smith. 241. Addition of dinitrogen tetroxide to olefins. Part II. Ethylene. Journal of the Chemical Society (Resumed). 1946: 1096 [2020-06-28]. ISSN 0368-1769. doi:10.1039/jr9460001096 (英语). 
  2. ^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2020-06-28].
  3. ^ Madhu Sudan Manna, Santanu Mukherjee. Organocatalytic Enantioselective Formal C(sp 2 )–H Alkylation. Journal of the American Chemical Society. 2015-01-14, 137 (1): 130–133 [2020-06-28]. ISSN 0002-7863. doi:10.1021/ja5117556 (英语). 
  4. ^ Wayland E. Noland, Philip J. Hartman. The Nitroethylation of Indole. A New Synthesis of Tryptamine. Journal of the American Chemical Society. 1954-06, 76 (12): 3227–3228 [2020-06-28]. ISSN 0002-7863. doi:10.1021/ja01641a044 (英语). 
  5. ^ Jagat C. Borah, Siddhartha Gogoi, Joshodeep Boruwa, Nabin C. Barua. LaCl 3 · 7H 2 O‐Promoted Regioselective Ring Opening of Epoxides Using NaNO 2 in Ether–Water System: A Facile Synthesis of 2‐Nitroalcohols. Synthetic Communications. 2005-03, 35 (6): 873–878 [2020-06-28]. ISSN 0039-7911. doi:10.1081/SCC-200051043 (英语). 
  6. ^ Colin Philip Leslie. The stereochemistry of the SE2 reaction of pentadienylsilanes [Dissertation], 1994. Department of Chemistry, University of Cambridge. 1630067.