六氟合錫(IV)酸亞硝醯

六氟合錫(IV)酸亞硝醯是一種配位化合物,化學式為(NO)2[SnF6]。它可由(BrF2)2[SnF6]和NOBrF4反應得到,[1]或通過NOF(HF)3(可由NOCl和HF反應得到)和四氟化錫的反應製得。[2][3]

六氟合錫(IV)酸亞硝醯
識別
CAS號 19179-03-4  checkY
SMILES
 
  • [N+]=O.[N+]=O.[F-][Sn+4]([F-])([F-])([F-])([F-])[F-]
性質
化學式 F6N2O2Sn
摩爾質量 292.71 g·mol−1
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

編輯
  1. ^ Bouy, Pierre. Reactions in bromine trifluoride. Some fluorinated salts of nitrosonium. Ann. chim. (Paris) [13] (1959), 4, 853-890. AN: 1960:90606.
  2. ^ Seel, Fritz; Birnkraut, Walter; Werner, Dietmar. Nitrosylfluoride-hydrogen fluorides. Chemische Berichte (1962), 95, 1264-1274.
  3. ^ Stephen J. Kuhn. Nitronium and nitrosonium salts. III. Preparation of nitronium and nitrosonium salts by the interaction of nitryl and nitrosyl chloride with anhydrous HF and Lewis acid fluorides. Canadian Journal of Chemistry, 1967. doi:10.1139/v67-517.