3-三丁基錫基吡啶

化合物

3-三丁基錫基吡啶是一種有機錫化合物,化學式為C17H31NSn。它可由3-溴吡啶正丁基鋰(或叔丁基鋰[2])反應,再與三丁基氯化錫反應製得。[3]它和碘甲烷乙醚中反應,可以得到1-甲基-3-三丁基錫基吡啶鎓碘化物;和對甲苯磺酸甲酯德語P-Toluolsulfonsäuremethylester乙酸乙酯中反應,可以得到1-甲基-3-三丁基錫基吡啶鎓對甲苯磺酸鹽。[4]

3-三丁基錫基吡啶
識別
CAS號 59020-10-9  checkY
PubChem 3483848
SMILES
 
  • N=1C=CC=C(C1)[Sn](CCCC)(CCCC)CCCC
性質
化學式 C17H31NSn
摩爾質量 368.14 g·mol−1
外觀 無色油狀物[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

編輯
  1. ^ Huifeng Yue; Chen Zhu; Magnus Rueping. Org. Lett. 2018, 20, 2, 385–388. doi:10.1021/acs.orglett.7b03669.
  2. ^ Nitration of heteroaryltrimethyltins by tetranitromethane and dinitrogen tetroxide: Mechanistic aspects, scope and limitations. European Journal of Organic Chemistry (2003), (9), 1711-1721. doi:10.1002/ejoc.200210611
  3. ^ Kim, Mi-Kyung; Kim, Yun-Hi; Kwon, Soon-Ki; Chu, Chang-Woong. Antiaromatic compounds and organic light-emitting devices comprising the same. 2015. US20150357578 A1.
  4. ^ A General Method of Synthesis of Regiospecifically N-Oxidized or N-Quaternized Polyazines by Palladium-Catalyzed Cross-Coupling of N-Oxidized or N-Quaternized Hetaryl Stannanes. Journal of Organic Chemistry (1995), 60 (11), 3487-3493