5α-膽甾烷-3β-醇甲酸酯

5α-膽甾烷-3β-醇甲酸酯是一種有機化合物,化學式為C28H48O2。它可由5α-膽甾烷-3β-醇二甲基甲醯胺反應得到;[2]在二(三甲基矽基)氨基鉀的催化下,甲酸甲酯也可作為甲醯化試劑進行反應。[3]它可以被硼氫化鈉-三氟化硼還原為3-甲氧基-5α-膽甾烷。[4]

5α-膽甾烷-3β-醇甲酸酯
識別
CAS號 10437-24-8  checkY
性質
化學式 C28H48O2
摩爾質量 416.68 g·mol−1
熔點 117 °C(390 K)[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

編輯
  1. ^ Goswami, Papori; Hazarika, Saroj; Borah, Parinita; Chowdhury, Pritish. Chloro- or bromo-trimethylsilane induced rapid and quantitative acid-ester conversion for steroid based alcohols with various carboxylic acids under solvent free conditions. Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 2003. 42B (3): 678-682.
  2. ^ Z. Arnold. Synthetic reactions of dimethylformamide. IX. Synthesis of esters of formic acid. Collection of Czechoslovak Chemical Communications. 1961, 26 (6): 1723–1726 [2021-11-20]. ISSN 0010-0765. doi:10.1135/cccc19611723. (原始內容存檔於2022-02-24) (英語). 
  3. ^ Jared Fernando, Alison Levens, Daniel Moock, David Lupton. N-Heterocyclic Carbene Catalyzed Transformylation. Synthesis. 2017-08, 49 (15): 3505–3510 [2021-11-20]. ISSN 0039-7881. doi:10.1055/s-0036-1588449. (原始內容存檔於2018-06-03) (英語). 
  4. ^ George Pettit, Usha Ghatak, Brian Green, T Kasturi, David Piatak. Communications- Steroids and Related Natural Products. IV. Reduction of Lactones to Cyclic Ethers.. The Journal of Organic Chemistry. 1961-05, 26 (5): 1685–1686 [2021-11-20]. ISSN 0022-3263. doi:10.1021/jo01064a644 (英語).