5,15-二(五氟苯基)-10,20-二(4-吡啶基)卟啉
5,15-二(五氟苯基)-10,20-二(4-吡啶基)卟啉是一种有机化合物,化学式为C42H18F10N6。它可由五氟苯基二(2-吡咯基)甲烷和4-吡啶甲醛在三氟乙酸的存在下于二氯甲烷中反应得到[3],或直接在丙酸中反应制得。[1]它可以和过渡金属形成配位化合物。[1][4]
5,15-二(五氟苯基)-10,20-二(4-吡啶基)卟啉 | |
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识别 | |
CAS号 | 268735-00-8 ![]() |
性质 | |
化学式 | C42H18F10N6 |
摩尔质量 | 796.62 g·mol−1 |
外观 | 深紫色晶体[1] |
密度 | 1.535±0.06 g·cm−3(20 °C)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
编辑- ^ 1.0 1.1 1.2 Weixia Xu, Zengqi Zhang, Xin Zhao, Jun Li. Catalytically active metal organic framework based on a porphyrin modified by electron-withdrawing groups. Journal of Coordination Chemistry. 2017-02-16, 70 (4): 746–755 [2021-07-03]. ISSN 0095-8972. doi:10.1080/00958972.2016.1267728 (英语).
- ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2021 ACD/Labs). Retrieved from SciFinder. [2021-07-03].
- ^ Jagadeesan Ramesh, Subramaniam Sujatha, Chellaiah Arunkumar. Synthesis, structure, electrochemical, DNA interaction and antimicrobial studies of fluorinated trans-dicationic pyridinium porphyrins. RSC Advances. 2016, 6 (68): 63271–63285 [2021-07-03]. ISSN 2046-2069. doi:10.1039/C6RA09148B (英语).
- ^ Splan, Kathryn E.; Stern, Charlotte L.; Hupp, Joseph T. Two coordinatively linked supramolecular assemblies constructed from highly electron deficient porphyrins. Inorganica Chimica Acta. 2004, 357 (13): 4005–4014. ISSN 0020-1693. doi:10.1016/j.ica.2004.06.059.